A Dirhoda-Heterocyclic Carbene.
carbide complexes
carbodicarbenes
dirhoda-heterocyclic carbenes
metalla-aromaticity
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
09 Mar 2020
09 Mar 2020
Historique:
received:
03
10
2019
revised:
22
11
2019
pubmed:
19
12
2019
medline:
19
12
2019
entrez:
19
12
2019
Statut:
ppublish
Résumé
The linear μ-carbido complex [Rh
Identifiants
pubmed: 31849162
doi: 10.1002/anie.201912650
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4274-4277Subventions
Organisme : Australian Research Council
ID : DP190100723
Informations de copyright
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Herein we consider the μ-carbido ligand as a neutral carbon atom providing two valence electrons to each rhodium(I) center. An alternative, description would envisage a tetranionic (C4−) ion between two RhIII centers, although this is implausible in terms of electroneutrality arguments.
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