Comparison of xenon and gallium sources on the detection and mapping of lithium in Li-containing materials by using ToF-SIMS combined FIB-SEM.
FIB-SEM
Ga ion source
Li detection
ToF-SIMS
Xe ion source
Journal
Journal of microscopy
ISSN: 1365-2818
Titre abrégé: J Microsc
Pays: England
ID NLM: 0204522
Informations de publication
Date de publication:
Jan 2020
Jan 2020
Historique:
received:
25
03
2019
revised:
18
10
2019
accepted:
16
12
2019
pubmed:
20
12
2019
medline:
20
12
2019
entrez:
20
12
2019
Statut:
ppublish
Résumé
Li can find itself a wide range of applications since it is the lightest metal. However, Li detection by microscopy-based techniques is problematic because of the highly susceptible nature during electron beam irradiation. ToF-SIMS is a versatile technique to detect Li but the detection of light materials is also problematic due to the large ion contaminated zone and low sputtering yield. By combining ToF-SIMS with a recently launched Xe ion source FIB-SEM, which has small ion contamination and high sputtering yield features, can produce more realistic data at near surface and below the surface region especially for the detection of lightweight materials such as Li. In this study, Li detection and mapping capabilities of ToF-SIMS attached to the FIB-SEM with Ga and Xe ion sources were discussed for Al incorporated Li
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
42-48Subventions
Organisme : Anadolu Üniversitesi
ID : 1502F070
Informations de copyright
© 2019 The Authors Journal of Microscopy © 2019 Royal Microscopical Society.
Références
Bassim, N., Scott, K. & Giannuzzi, L.A. (2014) Recent advances in focused ion beam technology and applications. Mrs Bull. 39, 317-325.
Chang, T.C., Wang, J.Y., Chu, C.L. & Lee, S. (2006) Mechanical properties and microstructures of various Mg-Li alloys. Mater. Lett. 60, 3272-3276.
Dermenci, K.B., Cekic, E. & Turan, S. (2016) Al stabilized Li7La3Zr2O12 solid electrolytes for all-solid state Li-ion batteries. Int. J. Hydr. Energ. 41, 9860-9867.
Heile, A., Lipinsky, D., Wehbe, N. et al. (2008) Investigation of methods to enhance the secondary ion yields in TOF-SIMS of organic samples. Surf. Interf. Anal. 40, 538-542.
Hovington, P., Timoshevskii, V., Burgess, S., Demers, H., Statham, P., Gauvin, R. & Zaghib, K. (2016) Can we detect Li KX-ray in lithium compounds using energy dispersive spectroscopy? Scanning 38, 571-578.
Iyengar, G., Clarke, W. & Downing, R. (1990) Determination of boron and lithium in diverse biological matrices using neutron activation-mass spectrometry (NA-MS). Fresen. J. Analyt. Chem. 338, 562-566.
Kamitsos, E.I., Patsis, A.P., Karakassides, M.A. & Chryssikos, G.D. (1990) Infrared reflectance spectra of lithium borate glasses. J. Non-Cryst. Solids 126, 52-67.
Karen, A., Ito, K. & Kubo, Y. (2014) TOF-SIMS analysis of lithium air battery discharge products utilizing gas cluster ion beam sputtering for surface stabilization. Surf. Interf. Anal. 46, 344-347.
Kudela, S., Oswald, S., Kudela, S., Baunack, S. & Wetzig, K. (2004) The ion exchange promoted interfacial strength in magnesium based composites. J. Alloy Compd. 378, 127-131.
Lee, J.T., Nitta, N., Benson, J., Magasinski, A., Fuller, T.F. & Yushin, G. (2013) Comparative study of the solid electrolyte interphase on graphite in full Li-ion battery cells using X-ray photoelectron spectroscopy, secondary ion mass spectroscopy, and electron microscopy. Carbon, 56, 397-398.
Loho, C., Djenadic, R., Bruns, M., Clemens, O. & Hahn, H. (2017) Garnet-type Li7La3Zr2O12 solid electrolyte thin films grown by CO2-laser assisted CVD for all-solid-state batteries. J. Electrochem. Soc. 164, A6131-A6139.
Ota, H., Akai, T., Namita, H., Yamaguchi, S. & Nomura, M. (2003) XAFS and TOF-SIMS analysis of SEI layers on electrodes. J. Power Sour. 119, 567-571.
Ota, H., Sato, T., Suzuki, H. & Usami, T. (2001) TPD-GC/MS analysis of the solid electrolyte interface (SEI) on a graphite anode in the propylene carbonate/ethylene sulfite electrolyte system for lithium batteries. J. Pow. Sour. 97, 107-113.
Song, M.S., Kim, R.H., Baek, S.W., Lee, K.S., Park, K. & Benayad, A. (2014) Is Li4Ti5O12 a solid-electrolyte-interphase-free electrode material in Li-ion batteries? Reactivity between the Li4Ti5O12 electrode and electrolyte. J. Mater. Chem. A 2, 631-636.
Sui, T., Song, B.H., Dluhos, J., Lu, L. & Korsunsky, A.M. (2015) Nanoscale chemical mapping of Li-ion battery cathode material by FIB-SEM and TOE-SIMS multi-modal microscopy. Nano Energy 17, 254-260.
Tarascon, J.M. & Armand, M. (2001) Issues and challenges facing rechargeable lithium batteries. Nature 414, 359-367.
Terauchi, M., Koshiya, S., Satoh, F. et al. (2014) Chemical state information of bulk specimens obtained by SEM-based soft-X-ray emission spectrometry. Microsc. Microanal. 20, 692-697.
Wang, P.C., Shih, Y.T., Lin, M.C., Lin, H.C., Chen, M.J. & Lin, K.M. (2010) Improvement of wear and cavitation-erosion by ALD-deposited LiAlxOy films on an Mg-10Li-0.5Zn alloy. Surf. Coat. Tech. 204, 3707-3712.
Yabuuchi, N., Yoshii, K., Myung, S.T., Nakai, I. & Komaba, S. (2011) Detailed studies of a high-capacity electrode material for rechargeable batteries, Li2MnO3-LiCo1/3Ni1/3Mn1/3O2. J. Am. Chem. Soc. 133, 4404-4419.
Ziegler, J. (1996) SRIM: the stopping power and range of ions in matter, IBM manual. IBM Publication.