Metabisulfite as an Unconventional Reagent for Green Oxidation of Emerging Contaminants Using an Iron-Based Catalyst.
Journal
ACS omega
ISSN: 2470-1343
Titre abrégé: ACS Omega
Pays: United States
ID NLM: 101691658
Informations de publication
Date de publication:
10 Dec 2019
10 Dec 2019
Historique:
received:
20
09
2019
accepted:
13
11
2019
entrez:
21
12
2019
pubmed:
21
12
2019
medline:
21
12
2019
Statut:
epublish
Résumé
In this work, contaminants of emerging concern were catalytically degraded in the homogeneous phase with the use of unconventional green reagents. Three reagents, namely, sulfite, metabisulfite, and persulfate, were tested and compared with conventional hydrogen peroxide in the degradation process activated by Fe-TAML. The latter is a biodegradable, homogeneous tetra-amido macrocyclic ligand catalyst containing iron(III). Metabisulfite showed the highest efficiency among the three tested reagents, and its reactivity was similar to that of H
Identifiants
pubmed: 31858059
doi: 10.1021/acsomega.9b03088
pmc: PMC6906940
doi:
Types de publication
Journal Article
Langues
eng
Pagination
20732-20741Informations de copyright
Copyright © 2019 American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
Références
J Hazard Mater. 2019 Jan 15;362:436-450
pubmed: 30261437
J Hazard Mater. 2011 Jan 30;185(2-3):844-51
pubmed: 21093981
Science. 2002 Apr 12;296(5566):326-8
pubmed: 11951040
J Am Chem Soc. 2017 Jan 18;139(2):879-887
pubmed: 28045254
Environ Sci Technol. 2015 Jan 20;49(2):1043-50
pubmed: 25535799
Toxicology. 2004 May 20;198(1-3):239-48
pubmed: 15138047
J Am Chem Soc. 2008 Apr 2;130(13):4497-506
pubmed: 18335938
Environ Sci Technol. 2015 Sep 15;49(18):11105-14
pubmed: 26280905
Acc Chem Res. 2002 Sep;35(9):782-90
pubmed: 12234208
Analyst. 2007 Jan;132(1):54-8
pubmed: 17180180
Science. 2007 Feb 9;315(5813):835-8
pubmed: 17185561
Biochem Pharmacol. 1994 Mar 2;47(5):871-6
pubmed: 8135862
Anal Chim Acta. 2006 Aug 4;575(1):106-13
pubmed: 17723578
Angew Chem Int Ed Engl. 2006 Jun 12;45(24):3974-7
pubmed: 16673442
Sci Total Environ. 2009 Jul 1;407(14):4189-206
pubmed: 19419751
J Am Chem Soc. 2008 Nov 12;130(45):15116-26
pubmed: 18928252
Talanta. 2019 May 1;196:381-388
pubmed: 30683380
J Hazard Mater. 2004 Apr 30;108(1-2):1-7
pubmed: 15081159
ACS Omega. 2018 Aug 17;3(8):9407-9418
pubmed: 31459074
J Am Chem Soc. 2003 Oct 15;125(41):12378-9
pubmed: 14531659
Environ Sci Technol. 2008 Nov 15;42(22):8522-7
pubmed: 19068842
Inorg Chem. 1997 Jul 30;36(16):3488-3492
pubmed: 11670027
Science. 2007 Nov 2;318(5851):783-7
pubmed: 17975062
Chem Res Toxicol. 2008 Jan;21(1):70-83
pubmed: 18052394
Redox Rep. 2001;6(4):229-34
pubmed: 11642713
Ecotoxicol Environ Saf. 1979 Dec;3(4):451-3
pubmed: 535561