A Facilely Synthesized Dual-State Emission Platform for Picric Acid Detection and Latent Fingerprint Visualization.


Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
26 Feb 2020
Historique:
received: 14 11 2019
revised: 16 12 2019
pubmed: 31 12 2019
medline: 20 3 2020
entrez: 31 12 2019
Statut: ppublish

Résumé

To achieve a highly efficient, dual-state emission platform for picric acid (PA) detection and latent fingerprint (LFP) visualization, flexible alkyl chains have been facilely attached to the commercial organic dye 3,4,9,10-perylenetetracarboxylic dianhydride to provide the target perylenetetracarboxylate molecules PTCA-C4, PTCA-C6, and PTCA-C12. Interestingly, all these molecules exhibited impressive fluorescence characteristics with high photoluminescence quantum yields (PLQYs) of around 93.0 % in dilute solution. Also, emissive features were observed in the solid state because close molecular packing is prevented by the alkyl chains, especially for PTCA-C6, which has a high PLQY value of 49.0 %. Benefiting from its impressive fluorescence performance in both solution and as aggregates, PTCA-C6 was used as a dual-state emission platform for PA detection and also LFP visualization. For example, double-responsive fluorescence quenching in solution was observed in PA detection studies, resulting in high quenching constants (K

Identifiants

pubmed: 31886910
doi: 10.1002/chem.201905169
doi:

Substances chimiques

3,4,9,10-perylenetetracarboxylic dianhydride 0
Anhydrides 0
Fluorescent Dyes 0
Picrates 0
Perylene 5QD5427UN7
picric acid A49OS0F91S

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2741-2748

Subventions

Organisme : National Natural Science Foundation of China
ID : 21975197, 51603165 and 21674085
Organisme : The Young Talent Fund of University Association for Science and Technology in Shaanxi
ID : 20180601
Organisme : Natural Science Basic Research Plan in Shaanxi Province of China
ID : 2019JM-040
Organisme : Innovation Capability Support Program of Shaanxi
ID : 2018PT-28, 2017KTPT-04
Organisme : Fundamental Research Funds for the Central Universities
ID : xjj2016069
Organisme : Key Laboratory Construction Program of Xi'an Municipal Bureau of Science and Technology
ID : 201805056ZD7CG40

Informations de copyright

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Duo Xi (D)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Yanzi Xu (Y)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Ruohan Xu (R)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Zhi Wang (Z)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Daomeng Liu (D)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Qifei Shen (Q)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Ling Yue (L)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Dongfeng Dang (D)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

Lingjie Meng (L)

School of Science, Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Non-equilibrium Synthesis, and Modulation of Condensed Matter, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.
Instrumental Analysis Center, Xi'an Jiao Tong University, Xi'an, 710049, P.R. China.

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