Thermal, mechanical and viscoelastic properties of citric acid-crosslinked starch/cellulose composite foams.

Biocomposites Cross-linking Flexural properties Moisture absorption Starch/cellulose foam Viscoelastic properties

Journal

Carbohydrate polymers
ISSN: 1879-1344
Titre abrégé: Carbohydr Polym
Pays: England
ID NLM: 8307156

Informations de publication

Date de publication:
15 Feb 2020
Historique:
received: 14 08 2019
revised: 24 11 2019
accepted: 25 11 2019
entrez: 1 1 2020
pubmed: 1 1 2020
medline: 1 1 2020
Statut: ppublish

Résumé

In this work, biodegradable starch/cellulose composite foams were fabricated at 220 °C by compression moulding gelatinised starch containing cellulose fibres as a reinforcing agent and citric acid as a cross-linking agent. It was found that the stiffness, tensile strength, flexural strength, and hydrophobicity of the starch/cellulose composite foams increased, and water absorption capacity decreased with an increase in the concentration of citric acid. The tensile strength increased from 1.76 MPa for 0 % citric acid to 2.25 MPa for the starch/cellulose composite foam crosslinked with 5 % (w/w) citric acid. Similarly, the flexural modulus also increased from 445 MPa to 601.1 MPa, and the flexural strength from 3.76 MPa to 7.61 MPa, for the composite foam crosslinked with 5 % (w/w) citric acid. The crosslinked composite foams showed better thermal stability compared to the non-crosslinked composite foam. The resulting composite foams could be used as a biodegradable alternative to expanded polystyrene packaging.

Identifiants

pubmed: 31887917
pii: S0144-8617(19)31343-8
doi: 10.1016/j.carbpol.2019.115675
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

115675

Informations de copyright

Copyright © 2019 Elsevier Ltd. All rights reserved.

Auteurs

M M Hassan (MM)

Bioproduct and Fibre Technology Team, AgResearch Limited, 1365 Springs Road, Lincoln, 7647 Canterbury, New Zealand; Biopolymer Network (BPN), 49 Sala Street, Rotorua 3010, New Zealand. Electronic address: mahbubul.hassan@agresearch.co.nz.

N Tucker (N)

Bioresources Engineering and Chemistry Group, The New Zealand Institute for Plant & Food Research, Gerald Street, Lincoln, Canterbury 7608, New Zealand; Biopolymer Network (BPN), 49 Sala Street, Rotorua 3010, New Zealand.

M J Le Guen (MJ)

Biopolymers and Chemicals Team, Scion, 49 Sala Street, Rotorua 3010, New Zealand; Biopolymer Network (BPN), 49 Sala Street, Rotorua 3010, New Zealand.

Classifications MeSH