Benchmarking semiclassical and perturbative methods for real-time simulations of cavity-bound emission and interference.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
28 Dec 2019
Historique:
entrez: 3 1 2020
pubmed: 3 1 2020
medline: 3 1 2020
Statut: ppublish

Résumé

We benchmark a selection of semiclassical and perturbative dynamics techniques by investigating the correlated evolution of a cavity-bound atomic system to assess their applicability to study problems involving strong light-matter interactions in quantum cavities. The model system of interest features spontaneous emission, interference, and strong coupling behavior and necessitates the consideration of vacuum fluctuations and correlated light-matter dynamics. We compare a selection of approximate dynamics approaches including fewest switches surface hopping (FSSH), multitrajectory Ehrenfest dynamics, linearized semiclassical dynamics, and partially linearized semiclassical dynamics. Furthermore, investigating self-consistent perturbative methods, we apply the Bogoliubov-Born-Green-Kirkwood-Yvon hierarchy in the second Born approximation. With the exception of fewest switches surface hopping, all methods provide a reasonable level of accuracy for the correlated light-matter dynamics, with most methods lacking the capacity to fully capture interference effects.

Identifiants

pubmed: 31893926
doi: 10.1063/1.5128076
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

244113

Auteurs

Norah M Hoffmann (NM)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Christian Schäfer (C)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Niko Säkkinen (N)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Angel Rubio (A)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Heiko Appel (H)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Aaron Kelly (A)

Department of Physics, Max Planck Institute for the Structure and Dynamics of Matter and Center for Free-Electron Laser Science, 22761 Hamburg, Germany.

Classifications MeSH