Revealing Ultrafast Population Transfer between Nearly Degenerate Electronic States.
Journal
The journal of physical chemistry letters
ISSN: 1948-7185
Titre abrégé: J Phys Chem Lett
Pays: United States
ID NLM: 101526034
Informations de publication
Date de publication:
20 Feb 2020
20 Feb 2020
Historique:
pubmed:
11
1
2020
medline:
11
1
2020
entrez:
11
1
2020
Statut:
ppublish
Résumé
The response of a molecule to photoexcitation is governed by the coupling of its electronic states. However, if the energetic spacing between the electronically excited states at the Franck-Condon window becomes sufficiently small, it is infeasible to selectively excite and monitor individual states with conventional time-resolved spectroscopy, preventing insight into the energy transfer and relaxation dynamics of the molecule. Here, we demonstrate how the combination of time-resolved spectroscopy and extensive surface hopping dynamics simulations with a global fit approach on individually excited ensembles overcomes this limitation and resolves the dynamics in the n3p Rydberg states in acetone. Photoelectron transients of the three closely spaced states n3p
Identifiants
pubmed: 31918552
doi: 10.1021/acs.jpclett.9b03462
pmc: PMC7052817
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1443-1449Références
J Chem Phys. 2007 Apr 7;126(13):134114
pubmed: 17430023
J Phys Chem A. 2017 Aug 31;121(34):6398-6404
pubmed: 28737942
Wiley Interdiscip Rev Comput Mol Sci. 2018 Nov-Dec;8(6):e1370
pubmed: 30450129
J Chem Phys. 2016 Dec 7;145(21):214312
pubmed: 28799347
J Chem Theory Comput. 2019 Sep 10;15(9):5031-5045
pubmed: 31339716
J Phys Chem Lett. 2016 Jun 2;7(11):2100-12
pubmed: 27171314
Chem Soc Rev. 2009 Jun;38(6):1542-50
pubmed: 19587950
Nature. 2002 May 30;417(6888):533-5
pubmed: 12037563
Proc Natl Acad Sci U S A. 1990 Jul;87(13):5168-72
pubmed: 11607090
J Phys Chem A. 2016 Aug 18;120(32):6418-23
pubmed: 27459051
J Phys Chem A. 2019 Aug 15;123(32):6848-6853
pubmed: 31314525
J Phys Chem Lett. 2017 Aug 17;8(16):3840-3845
pubmed: 28766339
Phys Chem Chem Phys. 2008 Jan 28;10(4):550-60
pubmed: 18183316
Annu Rev Phys Chem. 2016 May 27;67:387-417
pubmed: 27215818
Nature. 2010 Sep 23;467(7314):440-3
pubmed: 20864998
J Phys Chem A. 2010 Apr 1;114(12):4058-64
pubmed: 20192202
J Phys Chem A. 2017 Mar 30;121(12):2361-2366
pubmed: 28267341
Chem Rev. 2004 Apr;104(4):1719-57
pubmed: 15080710
Annu Rev Phys Chem. 2018 Apr 20;69:427-450
pubmed: 29490199
J Chem Phys. 2011 Oct 28;135(16):164309
pubmed: 22047241
Nat Commun. 2019 Jul 16;10(1):3133
pubmed: 31311933
Phys Chem Chem Phys. 2018 Dec 19;21(1):57-69
pubmed: 30306987
Chem Sci. 2017 Aug 1;8(8):5682-5691
pubmed: 28989607
Biochim Biophys Acta. 2004 Jul 9;1657(2-3):82-104
pubmed: 15238266
J Chem Phys. 2018 Mar 28;148(12):124119
pubmed: 29604835
Dalton Trans. 2012 Nov 14;41(42):13022-9
pubmed: 22986807
Chemphyschem. 2002 Jan 18;3(1):79-97
pubmed: 12465478