Affecting an Ultra-High Work Function of Silver.

Kelvin probe doping metals redox trap effect silver work function

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
16 03 2020
Historique:
received: 25 09 2019
revised: 21 11 2019
pubmed: 11 1 2020
medline: 11 1 2020
entrez: 11 1 2020
Statut: ppublish

Résumé

An ultra-high increase in the WF of silver, from 4.26 to 7.42 eV, that is, an increase of up to circa 3.1 eV is reported. This is the highest WF increase on record for metals and is supported by recent computational studies which predict the potential ability to affect an increase of the WF of metals by more than 4 eV. We achieved the ultra-high increase by a new approach: Rather than using the common method of 2D adsorption of polar molecules layers on the metal surface, WF modifying components, l-cysteine and Zn(OH)

Identifiants

pubmed: 31923344
doi: 10.1002/anie.201912293
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4698-4704

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Références

N. D. Lang, W. Kohn, Phys. Rev. B 1971, 3, 1215.
I. H. Campbell, S. Rubin, T. A. Zawodzinski, J. D. Kress, R. L. Martin, D. L. Smith, N. N. Barashkov, J. P. Ferraris, Phys. Rev. B 1996, 54, R14321.
H. Zhang, J. Tang, Q. Zhang, G. Zhao, G. Yang, J. Zhang, O. Zhou, L. Qin, Adv. Mater. 2006, 18, 87-91.
J. P. Barnak, R. S. Chau, C. Liang, US Patent US7022559B2, 2006.
B. de Boer, A. Hadipour, M. M. Mandoc, T. van Woudenbergh, P. W. M. Blom, Adv. Mater. 2005, 17, 621-625.
M. L. Sushko, A. L. Shluger, Adv. Mater. 2009, 21, 1111-1114.
V. B. Engelkes, J. M. Beebe, C. D. Frisbie, J. Am. Chem. Soc. 2004, 126, 14287-14296.
O. T. Hofmann, D. A. Egger, E. Zojer, Nano Lett. 2010, 10, 4369-4374.
P. D. Taylor, D. A. Osborne, S. A. Tawfik, T. Morishita, M. J. S. Spencer, Phys. Chem. Chem. Phys. 2019, 21, 7165-7173.
O. T. Hofmann, H. Glowatzki, C. Bürker, G. M. Rangger, B. Bürker, J. Niederhausen, T. Hosokai, I. Salzmann, R.-P. Blum, R. Rieger, J. Phys. Chem. C 2017, 121, 24657-24668.
J. He, L. Iagher, L. Etgar, D. Avnir, Chem. Commun. 2018, 54, 7203-7206.
D. Avnir, Adv. Mater. 2018, 30, 1706804.
D. Avnir, Acc. Chem. Res. 2014, 47, 579-592.
N. Ralbag, M. Mann-Lahav, E. S. Davydova, U. Ash, R. Galed, M. Handl, R. Hiesgen, E. Magliocca, W. Mustain, J. He, P. Cong, A. M. Beale, G. S. Grader, D. Avnir, D. R. Dekel, Matter 2019, 1, 959-975.
T. S. Bauer, B. Menagen, D. Avnir, Z. Hayouka, Sci. Rep. 2019, 9, 1-8.
B. Menagen, D. Avnir, ACS Biomater. Sci. Eng. 2019, 5, 2355-2364.
L. Shapiro, D. Avnir, ChemCatChem 2017, 9, 816-823.
N. Ralbag, I. Felner, D. Avnir, Phys. Rev. B 2019, 99, 64411.
R. Ben-Knaz, D. Avnir, Biomaterials 2009, 30, 1263-1267.
P. Li, Z. P. Xu, M. A. Hampton, D. T. Vu, L. Huang, V. Rudolph, A. V. Nguyen, J. Phys. Chem. C 2012, 116, 10325-10332.
V. Shkirskiy, P. Keil, H. Hintze-Bruening, F. Leroux, F. Brisset, K. Ogle, P. Volovitch, Corros. Sci. 2015, 100, 101-112.
N. Pace, E. Weerapana, Biomolecules 2014, 4, 419-434.
F. D. Urnov, J. C. Miller, Y.-L. Lee, C. M. Beausejour, J. M. Rock, S. Augustus, A. C. Jamieson, M. H. Porteus, P. D. Gregory, M. C. Holmes, Nature 2005, 435, 646.
M. Bibikova, K. Beumer, J. K. Trautman, D. Carroll, Science 2003, 300, 764.
W. Maret, Antioxid. Redox Signaling 2006, 8, 1419-1441.
K.-D. Kröncke, L.-O. Klotz, Antioxid. Redox Signaling 2009, 11, 1015-1027.
B. O. Leung, F. Jalilehvand, V. Mah, M. Parvez, Q. Wu, Inorg. Chem. 2013, 52, 4593-4602.
N. H. Helal, W. A. Badawy, Electrochim. Acta 2011, 56, 6581-6587.
M. B. Radovanović, M. B. Petrović, A. T. Simonović, S. M. Milić, M. M. Antonijević, Environ. Sci. Pollut. Res. 2013, 20, 4370-4381.
D. Kesavan, M. Gopiraman, N. Sulochana, Chem. Sci. Rev. Lett. 2012, 1, 1-8.
S. Fischer, A. C. Papageorgiou, M. Marschall, J. Reichert, K. Diller, F. Klappenberger, F. Allegretti, A. Nefedov, C. Wöll, J. V. Barth, J. Phys. Chem. C 2012, 116, 20356-20362.
Q. Chen, N. V. Richardson, Nat. Mater. 2003, 2, 324.
T. N. Ramesh, T. L. Madhu, Int. J. Inorg. Chem. 2015, 0, 536470.
A. K. Yadav, S. M. Haque, S. Tripathi, D. Shukla, M. A. Ahmed, D. M. Phase, S. Bandyopadhyay, S. N. Jha, D. Bhattacharyya, RSC Adv. 2016, 6, 74982-74990.
H. Behar-Levy, G. E. Shter, G. S. Grader, D. Avnir, Chem. Mater. 2004, 16, 3197-3202.
G. Nesher, M. Aylien, G. Sandaki, D. Avnir, G. Marom, Adv. Funct. Mater. 2009, 19, 1293-1298.
V. A. Yablokov, Y. A. Vasina, I. A. Zelyaev, S. V. Mitrofanova, Russ. J. Gen. Chem. 2009, 79, 1141.
S. Foley, M. Enescu, Vib. Spectrosc. 2007, 44, 256-265.
X. Wu, N. H. Bishopric, D. J. Discher, B. J. Murphy, K. A. Webster, Mol. Cell. Biol. 1996, 16, 1035-1046.
S. F. Parker, A. J. Ramirez-Cuesta, L. Daemen, Spectrochim. Acta Part A 2018, 190, 518-523.
S. F. Parker, F. Fernandez-Alonso, A. J. Ramirez-Cuesta, J. Tomkinson, S. Rudic, R. S. Pinna, G. Gorini, J. Fernández Castañon, J. Phys. Conf. Ser. 2014, 554, 012003.
K. M. Ismail, Electrochim. Acta 2007, 52, 7811-7819.
R. W. Zehner, B. F. Parsons, R. P. Hsung, L. R. Sita, Langmuir 1999, 15, 1121-1127.
S. Prada, U. Martinez, G. Pacchioni, Phys. Rev. B 2008, 78, 235423.
S. Choi, D.-H. Lee, S. G. Louie, J. Clarke, Phys. Rev. Lett. 2009, 103, 197001.
C. Cen, S. Thiel, G. Hammerl, C. W. Schneider, K. E. Andersen, C. S. Hellberg, J. Mannhart, J. Levy, Nat. Mater. 2008, 7, 298.
M. Sterrer, T. Risse, U. M. Pozzoni, L. Giordano, M. Heyde, H.-P. Rust, G. Pacchioni, H.-J. Freund, Phys. Rev. Lett. 2007, 98, 96107.
S. Lu, Z. Qin, Q. Guo, G. Cao, Appl. Surf. Sci. 2017, 392, 849-853.
L. Giordano, F. Cinquini, G. Pacchioni, Phys. Rev. B 2006, 73, 45414.
E. Zojer, T. C. Taucher, O. T. Hofmann, Adv. Mater. Interfaces 2019, 6, 1900581.
C. Hu, D. Liu, Y. Xiao, L. Dai, Prog. Nat. Sci. Mater. Int. 2018, 28, 121-132.

Auteurs

Jin He (J)

Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, 9190401, Israel.

Jeff Armstrong (J)

ISIS Facility, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, Oxfordshire, OX11 0QX, UK.

Peixi Cong (P)

Department of Chemistry, University College of London, Gordon Street, London, WC1H 0AJ, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, Oxfordshire, OX11 0FA, UK.

Barak Menagen (B)

Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, 9190401, Israel.

Lior Igaher (L)

Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, 9190401, Israel.

Andrew M Beale (AM)

Department of Chemistry, University College of London, Gordon Street, London, WC1H 0AJ, UK.
Research Complex at Harwell, Rutherford Appleton Laboratory, Harwell Oxford, Didcot, Oxfordshire, OX11 0FA, UK.

Lioz Etgar (L)

Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, 9190401, Israel.

David Avnir (D)

Institute of Chemistry and The Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem, 9190401, Israel.

Classifications MeSH