A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n-propyl moieties.


Journal

Dalton transactions (Cambridge, England : 2003)
ISSN: 1477-9234
Titre abrégé: Dalton Trans
Pays: England
ID NLM: 101176026

Informations de publication

Date de publication:
14 Feb 2020
Historique:
pubmed: 16 1 2020
medline: 16 1 2020
entrez: 16 1 2020
Statut: ppublish

Résumé

Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O

Identifiants

pubmed: 31939970
doi: 10.1039/c9dt04760c
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1721-1725

Auteurs

Hidetaka Nakai (H)

Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan. nakai@apch.kindai.ac.jp.

Seiya Miyata (S)

Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan. nakai@apch.kindai.ac.jp.

Yuu Kajiwara (Y)

Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan. nakai@apch.kindai.ac.jp.

Yoshiki Ozawa (Y)

Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Hyogo 678-1297, Japan.

Masaaki Abe (M)

Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Hyogo 678-1297, Japan.

Classifications MeSH