Interception of Elusive Cationic Hf-Al and Hf-Zn Heterobimetallic Adducts with Mixed Alkyl Bridges Featuring Multiple Agostic Interactions.
NMR spectroscopy
agostic interactions
chain shuttling
density functional calculation
hafnium
heterometallic complexes
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
23 Mar 2020
23 Mar 2020
Historique:
received:
18
12
2019
revised:
14
01
2020
pubmed:
17
1
2020
medline:
17
1
2020
entrez:
17
1
2020
Statut:
ppublish
Résumé
Heterobimetallic complexes with inequivalent bridging alkyl chains are very often invoked as key intermediates in many catalytic processes, yet their interception and structural characterization are lacking. Such complexes have been prepared from reactions of the cationic cyclometalated hafnocene [Cp
Identifiants
pubmed: 31943388
doi: 10.1002/chem.201905699
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
3758-3766Subventions
Organisme : Univation Technologies
Organisme : Dow Chemical Company
Organisme : CIRCC
Organisme : Università degli Studi di Perugia
ID : Progetto AMIS -Dipartimenti di Eccellenza
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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