Synthesis and Structure of Uranium-Silylene Complexes.
actinides
donor-acceptor interactions
heavy carbenes
silylenes
uranium
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
21 Feb 2020
21 Feb 2020
Historique:
received:
14
01
2020
pubmed:
18
1
2020
medline:
18
1
2020
entrez:
18
1
2020
Statut:
ppublish
Résumé
While carbene complexes of uranium have been known for over a decade, there are no reported examples of complexes between an actinide and a "heavy carbene." Herein, we report the syntheses and structures of the first uranium-heavy tetrylene complexes: (CpSiMe
Identifiants
pubmed: 31950554
doi: 10.1002/chem.202000214
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
2360-2364Subventions
Organisme : Office of Science
ID : DE-AC02-05CH11231
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Références
S. T. Liddle, Angew. Chem. Int. Ed. 2015, 54, 8604-8641;
Angew. Chem. 2015, 127, 8726-8764.
S. G. Minasian, J. L. Krinsky, J. D. Rinehart, R. Copping, T. Tyliszczak, M. Janousch, D. K. Shuh, J. Arnold, J. Am. Chem. Soc. 2009, 131, 13767-13783.
S. T. Liddle, J. McMaster, D. P. Mills, A. J. Blake, C. Jones, W. D. Woodul, Angew. Chem. Int. Ed. 2009, 48, 1077-1080;
Angew. Chem. 2009, 121, 1097-1100.
A. B. Altman, A. C. Brown, G. Rao, T. D. Lohrey, R. D. Britt, L. Maron, S. G. Minasian, D. K. Shuh, J. Arnold, Chem. Sci. 2018, 9, 4317-4324.
S. P. Vilanova, J. R. Walensky, Actinides: Pnictogen Complexes. In Encyclopedia of Inorganic and Bioinorganic Chemistry; R. A. Scott, Ed.; Wiley: Hoboken 2018.
M. Ephritikhine, Coord. Chem. Rev. 2016, 319, 35-62.
M. Porchia, U. Casellato, F. Ossola, G. Rossetto, P. Zanella, R. Graziani, J. Chem. Soc. Chem. Commun. 1986, 1034-1035.
P. L. Diaconescu, A. L. Odom, T. Agapie, C. C. Cummins, Organometallics 2001, 20, 4993-4995.
M. S. Winston, E. R. Batista, P. Yang, A. M. Tondreau, J. M. Boncella, Inorg. Chem. 2016, 55, 5534-5539.
T. Mehdoui, J.-C. Berthet, P. Thuéry, M. Ephritikhine, Chem. Commun. 2005, 2860-2862.
M.-T. Lee, C.-H. Hu, Organometallics 2004, 23, 976-983.
K. L. Nash, Separation Chemistry for Lanthanides and Trivalent Actinides. In Handbook on the Physics and Chemistry of Rare Earths; K. A. Gschneidner Jr., L. Eyring, G. R. Choppin, G. H. Lander, Eds.; Elsevier Science Amsterdam, 1994, Vol. 18, 197-238.
H. H. Dam, D. N. Reinhoudt, W. Verboom, Chem. Soc. Rev. 2007, 36, 367-377.
P. L. Arnold, S. T. Liddle, Chem. Commun. 2006, 3959-3971.
S. Hameury, P. de Frémont, P. Braunstein, Chem. Soc. Rev. 2017, 46, 632-733.
M. A. Boreen, J. Arnold, Multiple Bonding in Actinide Chemistry. In Encyclopedia of Inorganic and Bioinorganic Chemistry (Ed. R. A. Scott), Wiley: Hoboken 2018.
X.-W. Chi, Q.-Y. Wu, J.-H. Lan, C.-Z. Wang, Q. Zhang, Z.-F. Chai, W.-Q. Shi, Organometallics 2019, 38, 1963-1972.
S. S. Sen, H. W. Roesky, D. Stern, J. Henn, D. Stalke, J. Am. Chem. Soc. 2010, 132, 1123-1126.
S. S. Sen, S. Khan, P. P. Samuel, H. W. Roesky, Chem. Sci. 2012, 3, 659-682.
L. Álvarez-Rodríguez, J. A. Cabeza, P. García-Álvarez, D. Polo, Coord. Chem. Rev. 2015, 300, 1-28.
R. Zitz, H. Arp, J. Hlina, M. Walewska, C. Marschner, T. Szilvási, B. Blom, J. Baumgartner, Inorg. Chem. 2015, 54, 3306-3315.
R. Azhakar, R. S. Ghadwal, H. W. Roesky, H. Wolf, D. Stalke, Organometallics 2012, 31, 4588-4592.
R. Azhakar, R. S. Ghadwal, H. W. Roesky, H. Wolf, D. Stalke, Chem. Commun. 2012, 48, 4561-4563.
J. G. Brennan, R. A. Andersen, J. L. Robbins, J. Am. Chem. Soc. 1986, 108, 335-336.
L. Maron, O. Eisenstein, R. A. Andersen, Organometallics 2009, 28, 3629-3635.
P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 186-197.
B. Cordero, V. Gómez, A. E. Platero-Prats, M. Revés, J. Echeverría, E. Cremades, F. Barragán, S. Alvarez, Dalton Trans. 2008, 2832-2838.
M. T. Gamer, P. W. Roesky, S. N. Konchenko, P. Nava, R. Ahlrichs, Angew. Chem. Int. Ed. 2006, 45, 4447-4451;
Angew. Chem. 2006, 118, 4558-4561.
W. J. Evans, J. M. Perotti, J. W. Ziller, D. F. Moser, R. West, Organometallics 2003, 22, 1160-1163.
P. L. Arnold, S. T. Liddle, J. McMaster, C. Jones, D. P. Mills, J. Am. Chem. Soc. 2007, 129, 5360-5361.
The uranium-silicon distances in 1 and 2 are significantly shorter (≈80 pm) than the sum of the van der Waals radii as estimated by Bondi (A. Bondi, J. Phys. Chem. 1964, 68, 441-451), suggesting a uranium-silicon bonding interaction. It is also worth noting that the van der Waals radius for uranium estimated by Bondi is much shorter (>40 pm) than more recent estimates (see, for example,
S. S. Batsanov, Inorg. Mater. 2001, 37, 871-885).
A. Zalkin, J. G. Brennan, R. A. Andersen, Acta Crystallogr. Sect. C 1988, 44, 2104-2106.
J.-C. Berthet, J.-F. Le Maréchal, M. Nierlich, M. Lance, J. Vigner, M. Ephritikhine, J. Organomet. Chem. 1991, 408, 335-341.
J.-C. Berthet, C. Villiers, J.-F. Le Maréchal, B. Delavaux-Nicot, M. Lance, M. Nierlich, J. Vigner, M. Ephritikhine, J. Organomet. Chem. 1992, 440, 53-65.
C. J. Windorff, M. R. MacDonald, K. R. Meihaus, J. W. Ziller, J. R. Long, W. J. Evans, Chem. Eur. J. 2016, 22, 772-782.
C.-W. So, H. W. Roesky, P. M. Gurubasavaraj, R. B. Oswald, M. T. Gamer, P. G. Jones, S. Blaurock, J. Am. Chem. Soc. 2007, 129, 12049-12054.
L. R. Morss, N. M. Edelstein, J. Fuger, J. J. Katz, The Chemistry of the Actinide and Transactinide Elements., Springer, 2006.
R. Tacke, T. Ribbeck, Dalton Trans. 2017, 46, 13628-13659.
C. J. Windorff, W. J. Evans, Organometallics 2014, 33, 3786-3791.
D. R. Kindra, W. J. Evans, Chem. Rev. 2014, 114, 8865-8882.
J. G. Brennan, R. A. Andersen, A. Zalkin, Inorg. Chem. 1986, 25, 1756-1760.
S. S. Sen, A. Jana, H. W. Roesky, C. Schulzke, Angew. Chem. Int. Ed. 2009, 48, 8536-8538;
Angew. Chem. 2009, 121, 8688-8690.
For examples of natural population analyses in amidinato-silylene transition-metal complexes, see the following:
K. Junold, J. A. Baus, C. Burschka, T. Vent-Schmidt, S. Riedel, R. Tacke, Inorg. Chem. 2013, 52, 11593-11599;
B. Blom, S. Enthaler, S. Inoue, E. Irran, M. Driess, J. Am. Chem. Soc. 2013, 135, 6703-6713.