The Role of the Organic Solvent Polarity in Isolating Uranyl Peroxide Capsule Fragments.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
03 Feb 2020
Historique:
pubmed: 22 1 2020
medline: 22 1 2020
entrez: 22 1 2020
Statut: ppublish

Résumé

Uranyl peroxide capsules are a fascinating class of polyoxometalates (POMs), discovered only in the 21st century. Understanding the reactivity between peroxide, alkali cations, and uranyl in alkaline solutions is important in nuclear science disciplines including mineralogy, nuclear energy, and legacy nuclear wastes. Here, we have developed a general procedure to isolate different fragments of the uranyl-peroxide POM capsules, using organic solvents to partially remove K

Identifiants

pubmed: 31961146
doi: 10.1021/acs.inorgchem.9b02660
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1633-1641

Auteurs

Ana Arteaga (A)

Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.

Debmalya Ray (D)

Department of Chemistry, Chemical Theory Center, and Minnesota Supercomputing Institute , University of Minnesota , Minneapolis , Minnesota 55455 , United States.

Elliot Glass (E)

Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.

Nicolas P Martin (NP)

Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.

Lev N Zakharov (LN)

Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.

Laura Gagliardi (L)

Department of Chemistry, Chemical Theory Center, and Minnesota Supercomputing Institute , University of Minnesota , Minneapolis , Minnesota 55455 , United States.

May Nyman (M)

Department of Chemistry , Oregon State University , Corvallis , Oregon 97331 , United States.

Classifications MeSH