Low-Energy Electron Escape from Liquid Interfaces: Charge and Quantum Effects.

The high surface sensitivity and controlled surface charge state of submicron sized droplets is exploited to study low-energy electron transport through liquid interfaces using photoelectron imaging. Already a few charges on a droplet are found to modify the photoelectron images significantly. For narrow escape barriers, the comparison with an electron scattering model reveals pronounced quantum effects in the form of above-barrier reflections at electron kinetic energies below about 1 eV. The observed susceptibility to the characteristics of the electron escape barrier might provide access to these properties for liquid interfaces, which are generally difficult to investigate.