Iron-Catalyzed Cleavage Reaction of Keto Acids with Aliphatic Aldehydes for the Synthesis of Ketones and Ketone Esters.

catalysis cross-coupling decarbonylation decarboxylation synthetic methods

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
01 Apr 2020
Historique:
received: 09 01 2020
pubmed: 6 2 2020
medline: 6 2 2020
entrez: 4 2 2020
Statut: ppublish

Résumé

The radical-radical coupling reaction is an important synthetic strategy. In this study, the iron-catalyzed radical-radical cross-coupling reaction based on the decarboxylation of keto acids and decarbonylation of aliphatic aldehydes to obtain valuable aryl ketones is reported for the first time. Remarkably, when tertiary aldehydes were used as carbonyl sources, ketone esters were selectively obtained instead of ketones. The gram-scale preparation of aryl ketone through this strategy was easily achieved by using only 3 mol % of the iron catalyst. As a proof-of-concept, the bioactive molecule flurprimidol was synthesized in two steps by using this strategy.

Identifiants

pubmed: 32012367
doi: 10.1002/chem.202000114
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

4246-4250

Subventions

Organisme : Key Project Program of the Educational Department of Hunan Province
ID : 18A069
Organisme : Scientific Research Foundation of Hunan Provincial Education Department
ID : 15B232
Organisme : National Natural Science Foundation of China
ID : 21402168

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Fangyuan Zhou (F)

The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education, The Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.

Lesong Li (L)

The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education, The Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.

Kao Lin (K)

The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education, The Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.

Feng Zhang (F)

College of Science, Hunan Agricultural University, Changsha, 410128, P. R. China.

Guo-Jun Deng (GJ)

The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education, The Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.

Hang Gong (H)

The Key Laboratory of Environmentally Friendly Chemistry and Application of the Ministry of Education, The Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China.

Classifications MeSH