Geochemical anomalies of potentially hazardous elements reflect catchment geology: An example from the Tyrrhenian coast of Italy.

Assessing soil contamination by hazardous metals and estimating the extent to which metal concentrations in surficial sediments may pose risks to human health are increasingly important environmental issues. An integrated sedimentological and geochemical study of 57 Holocene beach sands from the shallow subsurface (120-130 cm depth) of the heavily urbanized Tyrrhenian Sea coast of Italy (Tuscany and adjacent coastal stretches) allowed a remarkable compositional heterogeneity to be identified as a function of spatial variations in riverine sediment supply and alongshore sediment dispersal patterns. Concentrations of Cr, Ni, and As exceeding maximum permissible limits for recreational/industrial sites (150 mg/kg, 120 mg/kg, and 20 mg/kg, respectively) reveal spatial trends that fit the petrography of modern beach sands and closely reflect the geology of river catchments, thus indicating a geogenic origin. Extremely high concentrations of Cr (and Ni), even 10 times greater than threshold values, are interpreted to reflect sediment supply from river catchments rich in ultramafic rocks (ophiolite sequences of Cecina and Campiglia areas), with subsequent transport via the longshore drift. On the other hand, high As concentrations in the Campiglia region and along the southern stretch of coast reflect leaching of felsic volcanic and plutonic parent rocks and hydrothermal products related to the Tuscan and Roman magmatic provinces cropping out in the Fiora, Albegna, and Cornia river catchments. This study shows that coastal sediment derived from particular source rocks is likely to contain potentially harmful metals in predictable proportions, which may easily exceed maximum allowable concentrations. Assessing spatial distribution of such metals based on catchment geology and sediment transport pathways may help separate natural concentrations from the anthropogenic contribution, providing a valuable source of information for appropriate remediation strategies and management options.

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.