Activation of Aromatic C-F Bonds by a N-Heterocyclic Olefin (NHO).
C-F activation
N-heterocyclic olefins
alkenes
fluorine
nucleophilic substitution
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
12 May 2020
12 May 2020
Historique:
received:
17
01
2020
pubmed:
7
2
2020
medline:
7
2
2020
entrez:
7
2
2020
Statut:
ppublish
Résumé
A N-heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C-F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl-substituted alkenes in which the central carbon-carbon double bond is in a twisted geometry.
Identifiants
pubmed: 32027063
doi: 10.1002/chem.202000276
pmc: PMC7317942
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
5951-5955Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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