On the facile and accurate determination of the Pt content in standard carbon supported Pt fuel cell catalysts.

Carbon supported Pt nanoparticles Platinum Platinum content Polymer electrolyte membrane fuel cell catalysts

Journal

Analytica chimica acta
ISSN: 1873-4324
Titre abrégé: Anal Chim Acta
Pays: Netherlands
ID NLM: 0370534

Informations de publication

Date de publication:
08 Mar 2020
Historique:
received: 20 09 2019
revised: 04 12 2019
accepted: 05 12 2019
entrez: 8 2 2020
pubmed: 8 2 2020
medline: 8 2 2020
Statut: ppublish

Résumé

We introduce a new and straight-forward methodology to accurately determine the Pt content in polymer membrane electrolyte fuel cell (PEMFC) catalysts consisting of carbon supported Pt nanoparticles (Pt/C). The method is based on an indirect Pt proof (IPP) consisting of the oxidative removal of the carbon support, the digestion of the Pt in aqua regia followed by a replacement reaction to form Cu ions (CuCl

Identifiants

pubmed: 32029117
pii: S0003-2670(19)31446-1
doi: 10.1016/j.aca.2019.12.010
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

41-49

Informations de copyright

Copyright © 2019 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Jan Bucher (J)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland.

Jonathan Quinson (J)

Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark.

Andrea M Mingers (AM)

Max-Planck-Institut for Iron Research GmbH, Max-Planck-Straße 1, D-40237, Düsseldorf, Germany.

Damin Zhang (D)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland.

Matthias Arenz (M)

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012, Bern, Switzerland. Electronic address: matthias.arenz@dcb.unibe.ch.

Classifications MeSH