Triggered Release of Loads from Microcapsule-in-Microcapsule Hydrogel Microcarriers: En-Route to an "Artificial Pancreas".


Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
04 03 2020
Historique:
pubmed: 8 2 2020
medline: 20 4 2021
entrez: 8 2 2020
Statut: ppublish

Résumé

A method to assemble stimuli-responsive nucleic acid-based hydrogel-stabilized microcapsule-in-microcapsule systems is introduced. An inner aqueous compartment stabilized by a stimuli-responsive hydrogel-layer (∼150 nm) provides the inner microcapsule (diameter ∼2.5 μm). The inner microcapsule is separated from an outer aqueous compartment stabilized by an outer stimuli-responsive hydrogel layer (thickness of ∼150 nm) that yields the microcapsule-in-microcapsule system. Different loads, e.g., tetramethyl rhodamine-dextran (TMR-D) and CdSe/ZnS quantum dots (QDs), are loaded in the inner and outer aqueous compartments. The hydrogel layers exist in a higher stiffness state that prevents inter-reservoir or leakage of the loads from the respective aqueous compartments. Subjecting the inner hydrogel layer to Zn

Identifiants

pubmed: 32031792
doi: 10.1021/jacs.9b11847
pmc: PMC7467680
doi:

Substances chimiques

Cadmium Compounds 0
Capsules 0
DNA, Catalytic 0
Dextrans 0
Drug Carriers 0
Fluorescent Dyes 0
Fluoro-Ruby 0
Hydrogels 0
Insulin 0
Rhodamines 0
Selenium Compounds 0
Sulfides 0
Zinc Compounds 0
cadmium selenide A7F646JC5C
Glucose Oxidase EC 1.1.3.4
Calcium Carbonate H0G9379FGK
Glucose IY9XDZ35W2
zinc sulfide KPS085631O

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4223-4234

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Auteurs

Amit Fischer (A)

Institute of Chemistry, Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Sivan Lilienthal (S)

Institute of Chemistry, Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Margarita Vázquez-González (M)

Institute of Chemistry, Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Michael Fadeev (M)

Institute of Chemistry, Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Yang Sung Sohn (YS)

Institute of Life Science, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Rachel Nechushtai (R)

Institute of Life Science, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

Itamar Willner (I)

Institute of Chemistry, Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.

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Classifications MeSH