A practical method to account for random phase approximation effects on the dynamic scattering of multi-component polymer systems.
Journal
The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360
Informations de publication
Date de publication:
07 Feb 2020
07 Feb 2020
Historique:
entrez:
10
2
2020
pubmed:
10
2
2020
medline:
10
2
2020
Statut:
ppublish
Résumé
Investigations of polymer systems that rely on the interpretation of dynamical scattering results as, e.g., the structure factor S(Q, t) of single chains or chain sections may require the inclusion of effects, as described within the framework of the random phase approximation (RPA) for polymers. To do this in practice for the dynamic part of S(Q, t) beyond the initial slope is a challenge. Here, we present a method (and software) that allows a straightforward assessment of dynamical RPA effects and inclusion of these in the process/procedures of model fitting. Examples of applications to the interpretation of neutron spin-echo data multi-component polymer melts are shown.
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM