A practical method to account for random phase approximation effects on the dynamic scattering of multi-component polymer systems.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
07 Feb 2020
Historique:
entrez: 10 2 2020
pubmed: 10 2 2020
medline: 10 2 2020
Statut: ppublish

Résumé

Investigations of polymer systems that rely on the interpretation of dynamical scattering results as, e.g., the structure factor S(Q, t) of single chains or chain sections may require the inclusion of effects, as described within the framework of the random phase approximation (RPA) for polymers. To do this in practice for the dynamic part of S(Q, t) beyond the initial slope is a challenge. Here, we present a method (and software) that allows a straightforward assessment of dynamical RPA effects and inclusion of these in the process/procedures of model fitting. Examples of applications to the interpretation of neutron spin-echo data multi-component polymer melts are shown.

Identifiants

pubmed: 32035437
doi: 10.1063/1.5139712
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

054901

Auteurs

M Monkenbusch (M)

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS-1) and Institute for Complex Systems (ICS-1), 52425 Jülich, Germany.

M Kruteva (M)

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS-1) and Institute for Complex Systems (ICS-1), 52425 Jülich, Germany.

M Zamponi (M)

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstr. 1, 85748 Garching, Germany.

L Willner (L)

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS-1) and Institute for Complex Systems (ICS-1), 52425 Jülich, Germany.

I Hoffman (I)

Institut Laue-Langevin (ILL), 71 Avenue des Martyrs, 38000 Grenoble, France.

B Farago (B)

Institut Laue-Langevin (ILL), 71 Avenue des Martyrs, 38000 Grenoble, France.

D Richter (D)

Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS-1) and Institute for Complex Systems (ICS-1), 52425 Jülich, Germany.

Classifications MeSH