A Phosphinine-Derived 1-Phospha-7-Bora-Norbornadiene: Frustrated Lewis Pair Type Activation of Triple Bonds.
alkyne
frustrated Lewis pair
nitrile
norbornadiene
phosphinine
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
23 Jun 2020
23 Jun 2020
Historique:
received:
16
01
2020
revised:
12
02
2020
pubmed:
14
2
2020
medline:
14
2
2020
entrez:
14
2
2020
Statut:
ppublish
Résumé
Salt metathesis of 1-methyl-2,4,6-triphenylphosphacyclohexadienyl lithium and chlorobis(pentafluorophenyl)borane affords a 1-phospha-7-bora-norbornadiene derivative 2. The C≡N triple bonds of nitriles insert into the P-B bond of 2 with concomitant C-B bond cleavage, whereas the C≡C bonds of phenylacetylenes react with 2 to form λ
Identifiants
pubmed: 32052879
doi: 10.1002/chem.202000266
pmc: PMC7383905
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
7788-7800Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : WO1496/9-1
Organisme : Deutsche Forschungsgemeinschaft
ID : MU1657/5-1
Organisme : Alexander von Humboldt-Stiftung
ID : fellowship for experienced researchers
Organisme : Alexander von Humboldt-Stiftung
ID : postdoctoral fellowship
Organisme : Netherlands Organisation for Scientific Research
ID : Veni grant
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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