Synthesis of α,β- and β-Unsaturated Acids and Hydroxy Acids by Tandem Oxidation, Epoxidation, and Hydrolysis/Hydrogenation of Bioethanol Derivatives.
bioethanol
chemical building blocks
polyhydroxyalkanoates
tandem chemistry
unsaturated acids
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
04 05 2020
04 05 2020
Historique:
received:
08
02
2020
pubmed:
14
2
2020
medline:
14
2
2020
entrez:
14
2
2020
Statut:
ppublish
Résumé
We report a reaction platform for the synthesis of three different high-value specialty chemical building blocks starting from bio-ethanol, which might have an important impact in the implementation of biorefineries. First, oxidative dehydrogenation of ethanol to acetaldehyde generates an aldehyde-containing stream active for the production of C
Identifiants
pubmed: 32052908
doi: 10.1002/anie.202002049
pmc: PMC7217036
doi:
Types de publication
Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
7456-7460Informations de copyright
© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Références
ChemSusChem. 2016 Apr 7;9(7):736-48
pubmed: 26938793
Nat Commun. 2013;4:2141
pubmed: 23846730
Chem Rev. 2004 Jun;104(6):3037-58
pubmed: 15186187
Angew Chem Int Ed Engl. 2020 May 4;59(19):7456-7460
pubmed: 32052908
J Org Chem. 2008 Mar 21;73(6):2270-4
pubmed: 18288864
Chem Soc Rev. 2017 Nov 13;46(22):6855-6871
pubmed: 28932844