Design of non-ionic carbon superbases: second generation carbodiphosphoranes.
Journal
Chemical science
ISSN: 2041-6520
Titre abrégé: Chem Sci
Pays: England
ID NLM: 101545951
Informations de publication
Date de publication:
07 Nov 2019
07 Nov 2019
Historique:
received:
18
07
2019
accepted:
15
08
2019
entrez:
15
2
2020
pubmed:
15
2
2020
medline:
15
2
2020
Statut:
epublish
Résumé
A new generation of carbodiphosphoranes (CDPs), incorporating pyrrolidine, tetramethylguanidine, or tris(dimethylamino)phosphazene as substituents is introduced as the most powerful class of non-ionic carbon superbases on the basicity scale to date. The synthetic approach as well as NMR spectroscopic and structural characteristics in the free and protonated form are described. Investigation of basicity in solution and in the gas phase by experimental and theoretical means provides the to our knowledge first reported p
Identifiants
pubmed: 32055322
doi: 10.1039/c9sc03565f
pii: c9sc03565f
pmc: PMC6993619
doi:
Types de publication
Journal Article
Langues
eng
Pagination
9483-9492Informations de copyright
This journal is © The Royal Society of Chemistry 2019.
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