C2-H Arylation of Indoles Catalyzed by Palladium-Containing Metal-Organic-Framework in γ-Valerolactone.

biomass green solvents heterogeneous catalysis indole metal-organic framework

Journal

ChemSusChem
ISSN: 1864-564X
Titre abrégé: ChemSusChem
Pays: Germany
ID NLM: 101319536

Informations de publication

Date de publication:
22 May 2020
Historique:
received: 11 02 2020
pubmed: 16 2 2020
medline: 16 2 2020
entrez: 16 2 2020
Statut: ppublish

Résumé

An efficient and selective procedure was developed for the direct C2-H arylation of indoles using a Pd-loaded metal-organic framework (MOF) as a heterogeneous catalyst and the nontoxic biomass-derived solvent γ-valerolactone (GVL) as a reaction medium. The developed method allows for excellent yields and C-2 selectivity to be achieved and tolerates various substituents on the indole scaffold. The established conditions ensure the stability of the catalyst as well as recoverability, reusability, and low metal leaching into the solution.

Identifiants

pubmed: 32061039
doi: 10.1002/cssc.202000378
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

2786-2791

Subventions

Organisme : Ministero dell'Istruzione, dell'Università e della Ricerca
ID : AMIS - Dipartimenti di Eccellenza 2018-2022
Organisme : European Commission
ID : HCCAT grant agreement nº [720996].

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Ioannis Anastasiou (I)

Laboratory of Green SOC, Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto, 8, 06124, Perugia, Italy.

Niels Van Velthoven (N)

Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven, Celestijnenlaan 200F-box 2454, 3001, Leuven, Belgium.

Elena Tomarelli (E)

Laboratory of Green SOC, Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto, 8, 06124, Perugia, Italy.

Aurora Lombi (A)

Laboratory of Green SOC, Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto, 8, 06124, Perugia, Italy.

Daniela Lanari (D)

Dipartimento di Scienze Farmaceutiche, Università di Perugia, Via del Liceo, 1, 06123, Perugia, Italy.

Pei Liu (P)

Electron Microscopy for Materials Science, University of Antwerp, Groenenborgerlaan 171, 2020, Antwerp, Belgium.

Sara Bals (S)

Electron Microscopy for Materials Science, University of Antwerp, Groenenborgerlaan 171, 2020, Antwerp, Belgium.

Dirk E De Vos (DE)

Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven, Celestijnenlaan 200F-box 2454, 3001, Leuven, Belgium.

Luigi Vaccaro (L)

Laboratory of Green SOC, Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto, 8, 06124, Perugia, Italy.

Classifications MeSH