Reply to "Comment on 'Osmotic pressure of compressed lattice knots' ".


Journal

Physical review. E
ISSN: 2470-0053
Titre abrégé: Phys Rev E
Pays: United States
ID NLM: 101676019

Informations de publication

Date de publication:
Jan 2020
Historique:
received: 02 12 2019
entrez: 20 2 2020
pubmed: 20 2 2020
medline: 20 2 2020
Statut: ppublish

Résumé

The free energy of a model of uniformly weighted lattice knots of length n and knot type K confined to a lattice cube of side length L-1 is given by F_{L}(ϕ)=-1/Vlogp_{n,L}(K), where V=L^{3} and where ϕ=n/V is the concentration of monomers of the lattice knot in the confining cube. The limiting free energy of the model is F_{∞}(ϕ)=lim_{L→∞}F_{L}(ϕ) and the limiting osmotic pressure of monomers leaving the lattice knot to become solvent molecules is defined by Π_{∞}(ϕ)=ϕ^{2}d/dϕ[F_{∞}(ϕ)/ϕ]. I show that, under very mild assumptions, the functions P_{L}(ϕ)=ϕ^{2}d/dϕ[F_{L}(ϕ)/ϕ]|_{n} and Π_{L}(ϕ)=ϕ^{2}d/dϕ[F_{L}(ϕ)/ϕ]|_{L} are finite-size approximations of Π_{∞}(ϕ).

Identifiants

pubmed: 32069656
doi: 10.1103/PhysRevE.101.016502
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

016502

Auteurs

E J Janse van Rensburg (EJ)

Department of Mathematics & Statistics, York University, Toronto, Ontario, Canada M3J 1P3.

Classifications MeSH