Topological Engineering of Pt-Group-Metal-Based Chiral Crystals toward High-Efficiency Hydrogen Evolution Catalysts.

Pt-group metals chiral crystals electrocatalysts hydrogen evolution topological engineering

Journal

Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358

Informations de publication

Date de publication:
Apr 2020
Historique:
received: 30 12 2019
revised: 22 01 2020
pubmed: 23 2 2020
medline: 23 2 2020
entrez: 22 2 2020
Statut: ppublish

Résumé

It has been demonstrated that topological nontrivial surface states can favor heterogeneous catalysis processes such as the hydrogen evolution reaction (HER), but a further decrease in mass loading and an increase in activity are still highly challenging. The observation of massless chiral fermions associated with large topological charge and long Fermi arc (FA) surface states inspires the investigation of their relationship with the charge transfer and adsorption process in the HER. In this study, it is found that the HER efficiency of Pt-group metals can be boosted significantly by introducing topological order. A giant nontrivial topological energy window and a long topological surface FA are expected at the surface when forming chiral crystals in the space group of P2

Identifiants

pubmed: 32080900
doi: 10.1002/adma.201908518
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e1908518

Subventions

Organisme : European Research Council
ID : 742068
Pays : International
Organisme : European Research Council
ID : 291472
Pays : International

Informations de copyright

© 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Qun Yang (Q)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.

Guowei Li (G)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.

Kaustuv Manna (K)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.

Fengren Fan (F)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.

Claudia Felser (C)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.
Center for Nanoscale Systems, Faculty of Arts and Sciences, Harvard University, Oxford Str. 11, LISE 308, Cambridge, MA, 02138, USA.

Yan Sun (Y)

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, Dresden, 01187, Germany.

Classifications MeSH