Synthesis, liquid crystalline behaviour and structure-property relationships of 1,3-bis(5-substituted-1,3,4-oxadiazol-2-yl)benzenes.

dipole moment fluorine liquid crystal oxadiazole

Journal

Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746

Informations de publication

Date de publication:
2020
Historique:
received: 02 09 2019
accepted: 21 01 2020
entrez: 22 2 2020
pubmed: 23 2 2020
medline: 23 2 2020
Statut: epublish

Résumé

Two series containing 1,3-bis(1,3,4-oxadiazol-2-yl)benzene as a rigid core (RC) and alkyl or perfluoroalkyl as terminal chains were synthesized and characterized. Liquid crystal properties of the synthesized compounds have been investigated by polarizing optical microscopy, differential scanning calorimetry and X-ray diffraction techniques. Conformation effects of the synthesized products on the dipole moments were also investigated.

Identifiants

pubmed: 32082434
doi: 10.3762/bjoc.16.17
pmc: PMC7006484
doi:

Types de publication

Journal Article

Langues

eng

Pagination

149-158

Informations de copyright

Copyright © 2020, Mabrouki et al.; licensee Beilstein-Institut.

Références

Chem Soc Rev. 2007 Dec;36(12):2070-95
pubmed: 17982522
Top Curr Chem. 2012;318:1-108
pubmed: 22089090
Molecules. 2012 Aug 27;17(9):10192-231
pubmed: 22926303
J Phys Chem B. 2016 Mar 17;120(10):2829-37
pubmed: 26914988

Auteurs

Afef Mabrouki (A)

Laboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, Tunisia.

Malek Fouzai (M)

LR99ES16 Physics Laboratory of Soft Matter and Electromagnetic Modelling, University of Tunis El Manar, 2092, Tunis, Tunisia.

Armand Soldera (A)

Department of Chemistry, Quebec Center for Functional Materials, University of Sherbrooke, Sherbrooke, Québec, J1K 2R1, Canada.

Abdelkader Kriaa (A)

Laboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, Tunisia.

Ahmed Hedhli (A)

Laboratory of Molecular Organic Chemistry, National Higher Engineering School of Tunis, 5 avenue Taha Hussein, Montfleury, 1089, Tunis, Tunisia.

Classifications MeSH