Restricted Ion Transport by Plasticizing Side Chains in Polycarbonate-Based Solid Electrolytes.
Journal
Macromolecules
ISSN: 0024-9297
Titre abrégé: Macromolecules
Pays: United States
ID NLM: 0365316
Informations de publication
Date de publication:
11 Feb 2020
11 Feb 2020
Historique:
received:
10
09
2019
revised:
23
12
2019
entrez:
25
2
2020
pubmed:
25
2
2020
medline:
25
2
2020
Statut:
ppublish
Résumé
Increasing the ionic conductivity has for decades been an overriding goal in the development of solid polymer electrolytes. According to fundamental theories on ion transport mechanisms in polymers, the ionic conductivity is strongly correlated to free volume and segmental mobility of the polymer for the conventional transport processes. Therefore, incorporating plasticizing side chains onto the main chain of the polymer host often appears as a clear-cut strategy to improve the ionic conductivity of the system through lowering of the glass transition temperature (
Identifiants
pubmed: 32089567
doi: 10.1021/acs.macromol.9b01912
pmc: PMC7032846
doi:
Types de publication
Journal Article
Langues
eng
Pagination
764-774Informations de copyright
Copyright © 2020 American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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