Bis(imino)carbazolate: A Master Key for Barium Chemistry.
X-ray diffraction
alkaline-earth metals
barium
ligand design
structure elucidation
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
02 Jun 2020
02 Jun 2020
Historique:
received:
29
01
2020
pubmed:
25
2
2020
medline:
25
2
2020
entrez:
25
2
2020
Statut:
ppublish
Résumé
Reported here is a readily available bis(imino)carbazole-based proligand that constitutes a convenient entry point into the challenging synthetic molecular chemistry of barium. It enables the preparation of rare or even, up to now, unknown, solution-stable heteroleptic barium complexes. The syntheses and structural features for the first molecular barium fluoride and the first barium stannylide, with an unsupported Ba-Sn bond, are described, along with other carbazolate barium species: an amide (both a remarkably stable starting material and an excellent hydrophosphination precatalyst), iodide, and silanylide. DFT analysis of bonding patterns in the barium stannylide and barium silanylide highlights a prevailingly ionic barium-tetrelide bond with a small covalent contribution.
Identifiants
pubmed: 32091662
doi: 10.1002/anie.202001439
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
9120-9126Subventions
Organisme : Agence Nationale de la Recherche
ID : ANR-17-CE07-0017-01
Organisme : Grand Équipement National De Calcul Intensif
ID : A0050807367
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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CCDC 1973342 (1), 1973328 (2), 1973343 (3), 1973329 (4), and 1973337 (5) contain the supplementary crystallographic data for this paper. These data are provided free of charge by The Cambridge Crystallographic Data Centre.