Activated diffusiophoresis.


Journal

The Journal of chemical physics
ISSN: 1089-7690
Titre abrégé: J Chem Phys
Pays: United States
ID NLM: 0375360

Informations de publication

Date de publication:
28 Feb 2020
Historique:
entrez: 2 3 2020
pubmed: 3 3 2020
medline: 3 3 2020
Statut: ppublish

Résumé

Perturbations of fluid media can give rise to non-equilibrium dynamics, which may, in turn, cause motion of immersed inclusions or tracer particles. We consider perturbations ("activations") that are local in space and time, of a fluid density which is conserved, and study the resulting diffusiophoretic phenomena that emerge at a large distance. Specifically, we consider cases where the perturbations propagate diffusively, providing examples from passive and active matter for which this is expected to be the case. Activations can, for instance, be realized by sudden and local changes in interaction potentials of the medium or by local changes in its activity. Various analytical results are provided for the case of confinement by two parallel walls. We investigate the possibility of extracting work from inclusions, which are moving through the activated fluid. Furthermore, we show that a time-dependent density profile, created via suitable activation protocols, allows for the conveyance of inclusions along controlled and stable trajectories. In contrast, in states with a steady density, inclusions cannot be held at stable positions, reminiscent of Earnshaw's theorem of electrostatics. We expect these findings to be applicable in a range of experimental systems. The phenomena described here are argued to be distinct from other forms of phoresis such as thermophoresis.

Identifiants

pubmed: 32113334
doi: 10.1063/1.5139017
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

084109

Auteurs

Christian M Rohwer (CM)

Max Planck Institute for Intelligent Systems, Heisenbergstr. 3, 70569 Stuttgart, Germany.

Mehran Kardar (M)

Department of Physics, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Matthias Krüger (M)

Institute for Theoretical Physics, University of Göttingen, D-37077 Göttingen, Germany.

Classifications MeSH