Quaternized styryl-azinium fluorophores as cellular RNA-binders.


Journal

Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
ISSN: 1474-9092
Titre abrégé: Photochem Photobiol Sci
Pays: England
ID NLM: 101124451

Informations de publication

Date de publication:
01 Mar 2020
Historique:
pubmed: 10 3 2020
medline: 15 12 2020
entrez: 10 3 2020
Statut: ppublish

Résumé

The capability of three quaternized styryl-azinium iodides to bind cellular RNA has been tested by means of Fluorescence Confocal Microscopy imaging of stained MCF-7 cells treated with RNase. Their association constants have been estimated through spectrophotometric and fluorimetric titrations with tRNA and compared to their affinity toward DNA. Transient absorption spectroscopy with femtosecond resolution confirmed the binding of the investigated compounds with tRNA and shed new light on the excited state dynamics of their complexes, by revealing a significant lengthening of the lifetime of S

Identifiants

pubmed: 32147676
doi: 10.1039/c9pp00465c
pii: 10.1039/c9pp00465c
doi:

Substances chimiques

Fluorescent Dyes 0
Pyrazines 0
Styrenes 0
RNA 63231-63-0
Ribonucleases EC 3.1.-

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

362-370

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Auteurs

Valentina Botti (V)

Department of Chemistry, Biology and Biotechnology and Center of Excellence on Innovative Nanostructured Materials (CEMIN), University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy. valentinabotti.90@gmail.com.

Lorena Urbanelli (L)

Department of Chemistry, Biology and Biotechnology, University of Perugia, via del Giochetto, 06126, Perugia, Italy.

Krizia Sagini (K)

Department of Chemistry, Biology and Biotechnology, University of Perugia, via del Giochetto, 06126, Perugia, Italy.

Luigi Tarpani (L)

Department of Chemistry, Biology and Biotechnology and Center of Excellence on Innovative Nanostructured Materials (CEMIN), University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy.

Alessio Cesaretti (A)

Department of Chemistry, Biology and Biotechnology and Center of Excellence on Innovative Nanostructured Materials (CEMIN), University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy.

Cosimo G Fortuna (CG)

Department of Chemical Sciences, University of Catania, viale Andrea Doria 6, 95125, Catania, Italy.

Fausto Elisei (F)

Department of Chemistry, Biology and Biotechnology and Center of Excellence on Innovative Nanostructured Materials (CEMIN), University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy.

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