Trapping of Difluorocarbene by Frustrated Lewis Pairs.
difluorocarbene
frustrated Lewis pairs
intermediates
organofluorine
phosphinoboranes
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
20 Jul 2020
20 Jul 2020
Historique:
received:
27
01
2020
revised:
08
03
2020
pubmed:
12
3
2020
medline:
12
3
2020
entrez:
12
3
2020
Statut:
ppublish
Résumé
Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho-position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
Identifiants
pubmed: 32160367
doi: 10.1002/anie.202001354
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
12428-12431Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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