Resolution, structures, and vibrational circular dichroism of helicoidal trinickel and tricobalt paddlewheel complexes.
X-ray crystallography
arsenyl tartrate
chiral resolution
helicoidal chirality
paddlewheel complexes
vibrational circular dichroism
Journal
Chirality
ISSN: 1520-636X
Titre abrégé: Chirality
Pays: United States
ID NLM: 8914261
Informations de publication
Date de publication:
Jun 2020
Jun 2020
Historique:
received:
28
11
2019
revised:
29
01
2020
accepted:
11
02
2020
pubmed:
14
3
2020
medline:
14
3
2020
entrez:
14
3
2020
Statut:
ppublish
Résumé
It has been recently shown that enantiomers of the helicoidal paddlewheel complex [Co
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
753-764Subventions
Organisme : European Union
ID : 706556
Organisme : European Union
Organisme : Conseil Régional de la Nouvelle Aquitaine
Organisme : University of Bordeaux
Organisme : CNRS
Informations de copyright
© 2020 Wiley Periodicals, Inc.
Références
Berry JF. Extended metal atom chains. In: Cotton FA, Murillo CA, Walton RA, eds. Multiple Bonds between Metal Atoms. 3rd. ed. Boston, MA: Springer US; 2005:669-706.
Clérac R, Cotton FA, Dunbar KR, Lu T, Murillo CA, Wang X. New linear tricobalt complex of di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2][PF6]2. Inorg Chem. 2000;39(14):3065-3070.
Armstrong DW, Cotton FA, Petrovic AG, Polavarapu PL, Warnke MM. Resolution of enantiomers in solution and determination of the chirality of extended metal atom chains. Inorg Chem. 2007;46(5):1535-1537.
Warnke MM, Cotton FA, Armstrong DW. Enantioseparation of extended metal atom chain complexes: unique compounds of extraordinarily high specific rotation. Chirality. 2007;19(3):179-183.
Marcovich D, Tapscott RE. Carbon-13 NMR studies on arsenic(III) and antimony(III) dihydroxydicarboxylate complexes. J Am Chem Soc. 1980;102(18):5712-5717.
Srinivasan A, Cortijo M, Bulicanu V, et al. Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain. Chem Sci. 2018;9(5):1136-1143.
Valentín-Perez Á, Naim A, Hillard EA, Rosa P, Cortijo M. Enantiopure chiral coordination polymers based on polynuclear paddlewheel helices and arsenyl tartrate. Polymers. 2018;10(3):311, 1-11.
Naim A, Bouhadja Y, Cortijo M, et al. Design and study of structural linear and nonlinear optical properties of chiral [Fe (phen)3]2+ complexes. Inorg Chem. 2018;57(23):14501-14512.
Berry JF, Cotton FA, Daniels LM, Murillo CA, Wang X. Oxidation of Ni3(dpa)4Cl2 and Cu3(dpa)4Cl2: nickel−nickel bonding interaction, but no copper−copper bonds. Inorg Chem. 2003;42(7):2418-2427.
Bruker. APEX2, SADABS, and SAINT. Madison, Wisconsin, USA: Bruker AXS Inc.; 2012.
Sheldrick GM. A short history of SHELX. Acta Crystallogr. 2008;A64:112-122.
Sheldrick GM. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015;A71:3-8.
Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H. OLEX2: a complete structure solution, refinement and analysis program. J Appl Cryst. 2009;42(2):339-341.
Buffeteau T, Lagugné-Labarthet F, Sourisseau C. Vibrational circular dichroism in general anisotropic thin solid films: measurement and theoretical approach. Appl Spectrosc. 2005;59(6):732-745.
Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Petersson GA, Nakatsuji H, Li X, Caricato M, Marenich AV, Bloino J, Janesko BG, Gomperts R, Mennucci B, Hratchian HP. Gaussian 16, Revision B.01, 2016.
Berry JF, Cotton FA, Lu T, Murillo CA, Wang X. Enhancing the stability of trinickel molecular wires and switches: Ni36+/Ni37+. Inorg Chem. 2003;42(11):3595-3601.
Hsiao CJ, Lai SH, Chen IC, Wang WZ, Peng SM. Metal−metal bonding and structures of metal string complexes Cr3(dpa)4Cl2, Cr3(dpa)4(NCS)2, and [Cr3(dpa)4Cl2](PF6) from IR, Raman, and surface-enhanced Raman spectra. J Phys Chem A. 2008;112(51):13528-13534.
Lai SH, Hsiao CJ, Ling JW, Wang WZ, Peng SM, Chen IC. Metal-metal bonding in metal-string complexes M3(dpa)4X2 (M=Ni, Co, dpa=di(2-pyridyl)amido, and X=Cl, NCS) from resonance Raman and infrared spectroscopy. Chem Phys Lett. 2008;456(4-6):181-185.
Clérac R, Cotton FA, Daniels LM, et al. Linear tricobalt compounds with di(2-pyridyl)amide (dpa) ligands: temperature dependence of the structural and magnetic properties of symmetrical and unsymmetrical forms of Co3(dpa)4Cl2 in the solid state. J Am Chem Soc. 2000;122(26):6226-6236.
He Y, Cao X, Nafie LA, Freedman TB. Ab initio VCD calculation of a transition-metal containing molecule and a new intensity enhancement mechanism for VCD. J Am Chem Soc. 2001;123(45):11320-11321.
Johannessen C, Thulstrup PW. Vibrational circular dichroism spectroscopy of a spin-triplet bis-(biuretato) cobaltate (iii) coordination compound with low-lying electronic transitions. Dalton Trans. 2007;10:1028-1033.
Sato H, Taniguchi T, Nakahashi A, Monde K, Yamagishi A. Effects of central metal ions on vibrational circular dichroism spectra of tris-(β-diketonato)metal (III) complexes. Inorg Chem. 2007;46(16):6755-6766.
Pescitelli G, Lüdeke S, Górecki M, Di Bari L. Symmetry-dependent vibrational circular dichroism enhancement in Co(II) salicylaldiminato complexes. J Phys Chem Lett. 2019;10(3):650-654.
Nafie LA. Theory of vibrational circular dichroism and infrared absorption: extension to molecules with low-lying excited electronic states. J Phys Chem A. 2004;108(35):7222-7231.
Domingos SR, Hartl F, Buma WJ, Woutersen S. Switchable amplification of vibrational circular dichroism as a probe of local chiral structure. ChemPhysChem. 2015;16(16):3363-3373.
Domingos SR, Huerta-Viga A, Baji L, et al. Amplified vibrational circular dichroism as a probe of local biomolecular structure. J Am Chem Soc. 2014;136(9):3530-3535.
Domingos SR, Sanders HS, Hartl F, Buma WJ, Woutersen S. Switchable amplification of vibrational circular dichroism as a probe of local chiral structure. Angew Chem Int Ed. 2014;53(51):14042-14045.
Berardozzi R, Badetti E, Carmo dos Santos NA, et al. Co(II)-induced giant vibrational CD provides a new design of methods for rapid and sensitive chirality recognition. Chem Commun. 2016;52(54):8428-8431.
Arrico L, Angelici G, Di Bari L. Taking advantage of Co(II) induced enhanced VCD for the fast and sensitive determination of enantiomeric excess. Org Biomol Chem. 2017;15(46):9800-9803.
Bormett RW, Smith GD, Asher SA, Barrick D, Kurtz DM. Vibrational circular dichroism measurements of ligand vibrations in haem and non-haem metalloenzymes. Faraday Discuss. 1994;99:327-339.
Merten C, Hiller K, Xu Y. Effects of electron configuration and coordination number on the vibrational circular dichroism spectra of metal complexes of trans-1,2-diaminocyclohexane. Phys Chem Chem Phys. 2012;14(37):12884-12891.
Rohmer MM, Strich A, Bénard M, Malrieu JP. Metal-metal bond length variability in Co3(dipyridylamide)4Cl2: bond-stretch isomerism, crystal field effects, or spin transition process? A DFT study. J Am Chem Soc. 2001;123(37):9126-9134.
Kiehl P, Rohmer MM, Bénard M. Electron delocalization in nickel metallic wires: a DFT investigation of Ni3(dpa)4Cl2 and [Ni3(dpa)4]3+ (dpa = dipyridylamide) and extension to higher nuclearity chains. Inorg Chem. 2004;43(10):3151-3158.