Facile Synthesis of a Stable Side-on Phosphinyne Complex by Redox Driven Intramolecular Cyclisation.
alkyne complex
cyclisation mechanism
frustrated Lewis pair
non-innocent ligand
phosphinyne complex
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
04 Sep 2020
04 Sep 2020
Historique:
received:
20
12
2019
revised:
08
03
2020
pubmed:
18
3
2020
medline:
18
3
2020
entrez:
18
3
2020
Statut:
ppublish
Résumé
Alkyne complexes with vicinal substitution by a Lewis acid and a Lewis base at the coordinated alkyne are prospective frustrated Lewis pairs exhibiting a particular mutual distance and, hence, a specific activation potential. In this contribution, investigations on the generation of a W
Identifiants
pubmed: 32181544
doi: 10.1002/chem.201905750
pmc: PMC7540294
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
11492-11502Subventions
Organisme : Deutsche Forschungsgemeinschaft
ID : SE 890/7-1
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH GmbH.
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