Interplay of Electronic and Steric Effects to Yield Low-Temperature CO Oxidation at Metal Single Sites in Defect-Engineered HKUST-1.

MOFs density functional theory dioxygen activation reaction mechanism single-atom sites

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
22 Jun 2020
Historique:
received: 08 01 2020
revised: 18 03 2020
pubmed: 21 3 2020
medline: 21 3 2020
entrez: 21 3 2020
Statut: ppublish

Résumé

In contrast to catalytically active metal single atoms deposited on oxide nanoparticles, the crystalline nature of metal-organic frameworks (MOFs) allows for a thorough characterization of reaction mechanisms. Using defect-free HKUST-1 MOF thin films, we demonstrate that Cu

Identifiants

pubmed: 32196128
doi: 10.1002/anie.202000385
pmc: PMC7318571
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

10514-10518

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : 3DMM2O

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Weijia Wang (W)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Dmitry I Sharapa (DI)

Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Abhinav Chandresh (A)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Alexei Nefedov (A)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Stefan Heißler (S)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Lars Heinke (L)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Felix Studt (F)

Institute of Catalysis Research and Technology (IKFT), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Yuemin Wang (Y)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Christof Wöll (C)

Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344, Eggenstein-Leopoldshafen, Germany.

Classifications MeSH