A series of novel aryl-methanone derivatives as inhibitors of FMS-like tyrosine kinase 3 (FLT3) in FLT3-ITD-positive acute myeloid leukemia.


Journal

European journal of medicinal chemistry
ISSN: 1768-3254
Titre abrégé: Eur J Med Chem
Pays: France
ID NLM: 0420510

Informations de publication

Date de publication:
01 May 2020
Historique:
received: 04 11 2019
revised: 09 03 2020
accepted: 10 03 2020
pubmed: 22 3 2020
medline: 1 12 2020
entrez: 22 3 2020
Statut: ppublish

Résumé

Mutants of the FLT3 receptor tyrosine kinase (RTK) with duplications in the juxtamembrane domain (FLT3-ITD) act as drivers of acute myeloid leukemia (AML). Potent tyrosine kinase inhibitors (TKi) of FLT3-ITD entered clinical trials and showed a promising, but transient success due to the occurrence of secondary drug-resistant AML clones. A further caveat of drugs targeting FLT3-ITD is the co-targeting of other RTKs which are required for normal hematopoiesis. This is observed quite frequently. Therefore, novel drugs are necessary to treat AML effectively and safely. Recently bis(1H-indol-2-yl)methanones were found to inhibit FLT3 and PDGFR kinases. In order to optimize these agents we synthesized novel derivatives of these methanones with various substituents. Methanone 16 and its carbamate derivative 17b inhibit FLT3-ITD at least as potently as the TKi AC220 (quizartinib). Models indicate corresponding interactions of 16 and quizartinib with FLT3. The activity of 16 is accompanied by a high selectivity for FLT3-ITD.

Identifiants

pubmed: 32199135
pii: S0223-5234(20)30199-9
doi: 10.1016/j.ejmech.2020.112232
pii:
doi:

Substances chimiques

Antineoplastic Agents 0
Indoles 0
Protein Kinase Inhibitors 0
FLT3 protein, human EC 2.7.10.1
fms-Like Tyrosine Kinase 3 EC 2.7.10.1

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

112232

Informations de copyright

Copyright © 2020 Elsevier Masson SAS. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of competing interests The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Mahboobi, Siavosh; Sellmer, Andreas; Pongratz, Herwig; Pilsl, Bernardette; Krämer, Oliver; Beyer, Mandy are also the inventors of this entity: PCT Int. Appl. (2019), WO 2019034538 A1 20190221.

Auteurs

Andreas Sellmer (A)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Bernadette Pilsl (B)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Mandy Beyer (M)

Department of Toxicology, University Medical Center, Mainz, Germany.

Herwig Pongratz (H)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Lukas Wirth (L)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Sigurd Elz (S)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Stefan Dove (S)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany.

Sven Julian Henninger (SJ)

Department of Toxicology, University Medical Center, Mainz, Germany.

Karsten Spiekermann (K)

Department of Medicine III, University Hospital, LMU Munich, Germany.

Harald Polzer (H)

Department of Medicine III, University Hospital, LMU Munich, Germany.

Susan Klaeger (S)

Technische Universität München, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Germany.

Bernhard Kuster (B)

Technische Universität München, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Germany.

Frank D Böhmer (FD)

Universitätsklinikum Jena - Bachstrasse 18 - D-07743 Jena, Germany.

Heinz-Herbert Fiebig (HH)

4HF Biotec GmbH, Am Flughafen 14, 79108, Freiburg, Germany.

Oliver H Krämer (OH)

Department of Toxicology, University Medical Center, Mainz, Germany.

Siavosh Mahboobi (S)

Institute of Pharmacy, Faculty of Chemistry and Pharmacy, University of Regensburg, 93040, Regensburg, Germany. Electronic address: Siavosh.mahboobi@chemie.uni-regensburg.de.

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Classifications MeSH