Lewis acid capping of a uranium(v) nitride via a uranium(iii) azide molecular square.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
23 Apr 2020
23 Apr 2020
Historique:
pubmed:
25
3
2020
medline:
25
3
2020
entrez:
25
3
2020
Statut:
ppublish
Résumé
Reaction of (CpiPr4)2UI with NaN3 resulted in formation of tetrameric uranium(iii) azide-bridged 'molecular square' [(CpiPr4)2U(μ-η1:η1-N3)]4 (1). Addition of B(C6F5)3 to 1 induced loss of N2 at room temperature, yielding the uranium(v) borane-capped nitrido (CpiPr4)2U(μ-N)B(C6F5)3 (2).
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM