Experimental and Numerical Studies on Major Pyrolysis Properties of Flame Retardant PVC Cables Composed of Multiple Materials.

Flame retardant cables were investigated using thermo-gravimetric analysis to measure the reference temperature and reference rate required for a fire spread simulation using a Fire Dynamics Simulator (FDS). Sensitivity analysis was also performed to understand the effects of the reference temperature and rate on the pyrolysis reactions. A two-step pyrolysis reaction was typically observed regardless of the cable type, and each pyrolysis reaction could be attributed to single or multiple components depending on the cable type and reaction order. Although the structures, compositions, and insulation performances of the cables differed considerably, the reference temperatures of the two-step pyrolysis reaction were extremely similar regardless of the cable type. Conversely, the reference rates of the different types of cables varied significantly. The sensitivity analysis results indicate that the mean values of the reference temperature and rate are sufficient to simulate the pyrolysis reactions of flame retardant cables. The results obtained herein also suggest that the heat transfer and pyrolysis reaction path associated with the multi-layered cable structure may be more important for accurately determining the ignition and fire spread characteristics, which are attributable to differences in cable structure, composition, and insulation performance.