Copper-catalyzed remote C-H arylation of polycyclic aromatic hydrocarbons (PAHs).
C–H arylation
copper catalysis
nonprecious metal catalyst
polycyclic aromatic hydrocarbons (PAHs)
regioselectivity
Journal
Beilstein journal of organic chemistry
ISSN: 1860-5397
Titre abrégé: Beilstein J Org Chem
Pays: Germany
ID NLM: 101250746
Informations de publication
Date de publication:
2020
2020
Historique:
received:
18
01
2020
accepted:
06
03
2020
entrez:
14
4
2020
pubmed:
14
4
2020
medline:
14
4
2020
Statut:
epublish
Résumé
The regioselective C-H arylation of substituted polycyclic aromatic hydrocarbons (PAHs) is a desired but challenging task. A copper-catalyzed C7-H arylation of 1-naphthamides has been developed by using aryliodonium salts as arylating reagents. This protocol does not need to use precious metal catalysts and tolerates wide variety of functional groups. Under standard conditions, the remote C-H arylation of other PAHs including phenanthrene-9-carboxamide, pyrene-1-carboxamide and fluoranthene-3-carboxamide has also accomplished, which provides an opportunity for the development of diverse organic optoelectronic materials.
Identifiants
pubmed: 32280382
doi: 10.3762/bjoc.16.49
pmc: PMC7136547
doi:
Types de publication
Journal Article
Langues
eng
Pagination
530-536Informations de copyright
Copyright © 2020, Luo et al.; licensee Beilstein-Institut.
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