Expanding the Boxmi Ligand Family: Synthesis and Application of NON and NSN Ligands.


Journal

The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R

Informations de publication

Date de publication:
15 May 2020
Historique:
pubmed: 15 4 2020
medline: 15 4 2020
entrez: 15 4 2020
Statut: ppublish

Résumé

Two synthetic strategies for a new family of neutral NON ligands featuring a "bis(oxazolinylmethylidene)isobenzofuran" framework (boxman) are reported. A Pd-mediated cyclization reaction forming the isobenzofuran core constitutes the key reaction in the eight-step synthetic route to the nonbackbone-methylated target compound

Identifiants

pubmed: 32286820
doi: 10.1021/acs.joc.0c00751
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6719-6731

Auteurs

Clemens K Blasius (CK)

Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.

Bing-Tao Ren (BT)

The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China.

David Bürgy (D)

Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.

Yan-Kai Liu (YK)

The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China.

Bin Li (B)

The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China.

Ina Michalsky (I)

Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.

Hubert Wadepohl (H)

Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.

Qing-Hai Deng (QH)

The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China.

Lutz H Gade (LH)

Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, Heidelberg 69120, Germany.

Classifications MeSH