Charting the Metal-Dependent High-Pressure Stability of Bimetallic UiO-66 Materials.
Journal
ACS materials letters
ISSN: 2639-4979
Titre abrégé: ACS Mater Lett
Pays: United States
ID NLM: 101747116
Informations de publication
Date de publication:
06 Apr 2020
06 Apr 2020
Historique:
received:
06
02
2020
accepted:
20
03
2020
entrez:
17
4
2020
pubmed:
17
4
2020
medline:
17
4
2020
Statut:
ppublish
Résumé
In theory, bimetallic UiO-66(Zr:Ce) and UiO-66(Zr:Hf) metal-organic frameworks (MOFs) are extremely versatile and attractive nanoporous materials as they combine the high catalytic activity of UiO-66(Ce) or UiO-66(Hf) with the outstanding stability of UiO-66(Zr). Using in situ high-pressure powder X-ray diffraction, however, we observe that this expected mechanical stability is not achieved when incorporating cerium or hafnium in UiO-66(Zr). This observation is akin to the earlier observed reduced thermal stability of UiO-66(Zr:Ce) compounds. To elucidate the atomic origin of this phenomenon, we chart the loss-of-crystallinity pressures of 22 monometallic and bimetallic UiO-66 materials and systematically isolate their intrinsic mechanical stability from their defect-induced weakening. This complementary experimental/computational approach reveals that the intrinsic mechanical stability of these bimetallic MOFs decreases nonlinearly upon cerium incorporation but remains unaffected by the zirconium: hafnium ratio. Additionally, all experimental samples suffer from defect-induced weakening, a synthesis-controlled effect that is observed to be independent of their intrinsic stability.
Identifiants
pubmed: 32296781
doi: 10.1021/acsmaterialslett.0c00042
pmc: PMC7147928
doi:
Types de publication
Journal Article
Langues
eng
Pagination
438-445Informations de copyright
Copyright © 2020 American Chemical Society.
Déclaration de conflit d'intérêts
The authors declare no competing financial interest.
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