Dialkenylgermanes as Precursors of Silsesquioxane-based Macromolecular Structures.

allylgermanes hydrosilylation silsesquioxanes spherosilicates vinylgermanes

Journal

Chemistry, an Asian journal

ISSN: 1861-471X

Titre abrégé: Chem Asian J

Pays: Germany

ID NLM: 101294643

Informations de publication

Date de publication:
15 May 2020

Historique:

received: 17 03 2020

pubmed: 18 4 2020

medline: 18 4 2020

entrez: 18 4 2020

Statut: ppublish

Résumé

Herein we report a study of highly efficient platinum-catalyzed hydrosilylation of dialkenylgermanes with silsesquioxanes and spherosilicates. The use of divinyl- and diallylgermanes allowed the synthesis of new classes of compounds, i. e., dumbbell-type systems, silsesquioxanes with alkenyl pendant group, and oligomeric derivatives. The results are supported by detailed data from in situ FT-IR and NMR measurements, enabling precise monitoring of the reaction progress and determination of regioselectivity of the formed products.

Identifiants

DOI: 10.1002/asia.202000353 PMID: 32301555

pubmed: 32301555

doi: 10.1002/asia.202000353

doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

Pagination

1598-1604

Subventions

Organisme : National Science Centre (Poland)

ID : UMO-2017/27/B/ST5/00149

Organisme : National Science Centre (Poland)

ID : UMO-2017/25/N/ST5/00404

Organisme : Adam Mickiewicz University Foundation

Informations de copyright

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