Evidence of Alpha Radiolysis in the Formation of a Californium Nitrate Complex.

californium electronic structure analysis f-element radiolysis

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
22 Jul 2020
Historique:
received: 19 04 2020
pubmed: 22 4 2020
medline: 22 4 2020
entrez: 22 4 2020
Statut: ppublish

Résumé

Well-characterized complexes of transplutonium elements are scarce because of the experimental challenges of working with these elements and the rarity of the isotopes. This leads to a lack of structural and spectroscopic data needed to understand the nature of chemical bonds in these compounds. In this work, the synthesis of Cf(DOPO

Identifiants

pubmed: 32315469
doi: 10.1002/chem.202001904
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

8885-8888

Subventions

Organisme : Office of Science
ID : DE-SC0008479
Organisme : Office of Science
ID : DE-SC002183
Organisme : Office of Science
ID : DE-FG02-13ER16414
Organisme : Office of Science
ID : DE-AC02-05CH11231
Organisme : National Science Foundation
ID : CHE 1625543

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Références

T. E. Albrecht-Schmitt, Inorg. Chem. 2019, 58, 1721-1723.
N. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, 1997.
F. D. White, D. Dan, T. E. Albrecht-Schmitt, Chem. Eur. J. 2019, 25, 10251-10261.
S. K. Cary, M. Vasiliu, R. E. Baumbach, J. T. Stritzinger, T. D. Green, K. Diefenbach, J. N. Cross, K. L. Knappenberger, G. Liu, M. A. Silver, Nat. Commun. 2015, 6, 6827.
S. Galley, S. Pattenaude, C. A. Gaggioli, Y. Qiao, J. Sperling, M. Zeller, S. Pakhira, J. Mendoza-Cortes, E. Schelter, T. Albrecht-Schmitt, L. Gagliardi, S. C. Bart, J. Am. Chem. Soc. 2019, 141, 2356-2366.
S. S. Galley, J. M. Sperling, C. J. Windorff, M. Zeller, T. E. Albrecht-Schmitt, S. C. Bart, Organometallics 2019, 38, 606-609.
F. Baumgärtner, E. O. Fischer, B. Kanellak, P. Lauberea, Angew. Chem. Int. Ed. Engl. 1966, 5, 134-135;
Angew. Chem. 1966, 78, 112-113.
M. J. Polinski, E. B. Garner III, R. Maurice, N. Planas, J. T. Stritzinger, T. G. Parker, J. N. Cross, T. D. Green, E. V. Alekseev, S. M. Van Cleve, W. Depmeier, L. Gagliardi, M. Shatruk, K. L. Knappenberger, G. Liu, S. Skanthakumar, L. Soderholm, D. A Dixon, T. E. Albrecht-Schmitt, Nat. Chem. 2014, 6, 387-392.
M. J. Polinski, K. A. Pace, J. T. Stritzinger, J. Lin, J. N. Cross, S. K. Cary, S. M. Van Cleve, E. V. Alekseev, T. E. Albrecht-Schmitt, Chem. Eur. J. 2014, 20, 9892-9896.
R. E. Sykora, Z. Assefa, R. G. Haire, T. E. Albrecht-Schmitt, Inorg. Chem. 2006, 45, 475-477.
D. Rai, R. G. Strickert, J. L. Ryan, Inorg. Nucl. Chem. Lett. 1980, 16, 551-555.
L. G. Ranis, K. Werellapatha, N. J. Pietrini, B. A. Bunker, S. N. Brown, Inorg. Chem. 2014, 53, 10203-10216.
S. A. Pattenaude, C. S. Kuehner, W. L. Dorfner, E. J. Schelter, P. E. Fanwick, S. C. Bart, Inorg. Chem. 2015, 54, 6520-6527.
L. Gagliardi, R. Lindh, G. Karlström, J. Chem. Phys. 2004, 121, 4494-4500.

Auteurs

Shane S Galley (SS)

H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907, USA.

Carlo Alberto Gaggioli (CA)

Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota, 55455, USA.

Matthias Zeller (M)

H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907, USA.

Cristian Celis-Barros (C)

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida, 32306, USA.

Thomas E Albrecht-Schmitt (TE)

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida, 32306, USA.

Laura Gagliardi (L)

Department of Chemistry, Supercomputing Institute, and Chemical Theory Center, University of Minnesota, Minneapolis, Minnesota, 55455, USA.

Suzanne C Bart (SC)

H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana, 47907, USA.

Classifications MeSH