Synthesis, Photophysical and Electronic Properties of Mono-, Di-, and Tri-Amino-Substituted Ortho-Perylenes, and Comparison to the Tetra-Substituted Derivative.
borylation
intersystem crossing
luminescence
polycyclic aromatic hydrocarbon
triarylamine
Journal
Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783
Informations de publication
Date de publication:
16 Sep 2020
16 Sep 2020
Historique:
received:
26
03
2020
revised:
16
04
2020
pubmed:
25
4
2020
medline:
25
4
2020
entrez:
25
4
2020
Statut:
ppublish
Résumé
We synthesized a series of new mono-, di-, tri- and tetra-substituted perylene derivatives with strong bis(para-methoxyphenyl)amine (DPA) donors at the uncommon 2,5,8,11-positions. The properties of our new donor-substituted perylenes were studied in detail to establish a structure-property relationship. Interesting trends and unusual properties are observed for this series of new perylene derivatives, such as a decreasing charge transfer (CT) character with increasing number of DPA moieties and individual reversible oxidations for each DPA moiety. Thus, (DPA)-Per possesses one reversible oxidation while (DPA)
Identifiants
pubmed: 32329914
doi: 10.1002/chem.202001475
pmc: PMC7540539
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
12050-12059Subventions
Organisme : DFG
ID : MA 4471/8-1
Organisme : DFG
ID : GRK 2112
Organisme : Bayerisches Staatsministerium für Wissenschaft, Forschung und Kunst
ID : "Solar Technologies go Hybrid"
Informations de copyright
© 2020 The Authors. Published by Wiley-VCH GmbH.
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