Synthesis and carbonic anhydrase activating properties of a series of 2-amino-imidazolines structurally related to clonidine


Journal

Journal of enzyme inhibition and medicinal chemistry
ISSN: 1475-6374
Titre abrégé: J Enzyme Inhib Med Chem
Pays: England
ID NLM: 101150203

Informations de publication

Date de publication:
Dec 2020
Historique:
entrez: 28 4 2020
pubmed: 28 4 2020
medline: 2 1 2021
Statut: ppublish

Résumé

The Carbonic Anhydrase (CA, EC 4.2.1.1) activating properties of histamine have been known for a long time. This compound has been extensively modified but only in few instances the imidazole ring has been replaced with other heterocycles. It was envisaged that the imidazoline ring could be a bioisoster of the imidazole moiety. Indeed, we report that clonidine, a 2-aminoimidazoline derivative, was found able to activate several human CA isoforms (hCA I, IV, VA, VII, IX, XII and XIII), with potency in the micromolar range, while it was inactive on hCA II. A series of 2-aminoimidazoline, structurally related to clonidine, was then synthesised and tested on selected hCA isoforms. The compounds were inactive on hCA II while displayed activating properties on hCA I, VA, VII and XIII, with K

Identifiants

pubmed: 32336172
doi: 10.1080/14756366.2020.1749602
pmc: PMC7241460
doi:

Substances chimiques

2-aminoimidazolone 0
Carbonic Anhydrase Inhibitors 0
Imidazoles 0
Isoenzymes 0
Carbonic Anhydrases EC 4.2.1.1
Clonidine MN3L5RMN02

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1003-1010

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Auteurs

Niccolò Chiaramonte (N)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Soumia Maach (S)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Caterina Biliotti (C)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Andrea Angeli (A)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Gianluca Bartolucci (G)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Laura Braconi (L)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Silvia Dei (S)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Elisabetta Teodori (E)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Claudiu T Supuran (CT)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

Maria Novella Romanelli (MN)

Section of Pharmaceutical and Nutraceutical Sciences, Department of Neuroscience, Psychology, Drug Research and Child's Health, University of Florence, Sesto Fiorentino, Italy.

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Classifications MeSH