Dinuclear Gold(I) Complexes Bearing N,N'-Allyl-Bridged Bisimidazolylidene Ligands.
Gold
Isomerisation
N-Heterocyclic Carbenes
Photochemistry
Silver
Journal
Chemistry, an Asian journal
ISSN: 1861-471X
Titre abrégé: Chem Asian J
Pays: Germany
ID NLM: 101294643
Informations de publication
Date de publication:
17 Jun 2020
17 Jun 2020
Historique:
received:
08
04
2020
revised:
28
04
2020
pubmed:
30
4
2020
medline:
30
4
2020
entrez:
30
4
2020
Statut:
ppublish
Résumé
A novel N,N'-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II).
Identifiants
pubmed: 32348033
doi: 10.1002/asia.202000453
pmc: PMC7687270
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
1848-1851Subventions
Organisme : TUM Graduate School
Organisme : Fundação para a Ciência e a Tecnologia, Portugal
ID : UID/Multi/04349/2019
Organisme : Fundação para a Ciência e a Tecnologia, Portugal
ID : PTDC/QUI-NUC/30147/2017
Organisme : Bach
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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