The Fedorov-Groth law revisited: complexity analysis using mineralogical data.

Fedorov–Groth law Shannon information chemical composition complexity symmetry

Journal

Acta crystallographica. Section A, Foundations and advances
ISSN: 2053-2733
Titre abrégé: Acta Crystallogr A Found Adv
Pays: United States
ID NLM: 101620182

Informations de publication

Date de publication:
01 May 2020
Historique:
received: 27 02 2020
accepted: 26 03 2020
entrez: 2 5 2020
pubmed: 2 5 2020
medline: 2 5 2020
Statut: ppublish

Résumé

The Fedorov-Groth law points out that, on average, chemical simplicity corresponds to higher symmetry, and chemically complex compounds usually have lower symmetry than chemically simple compounds. Using mineralogical data, it is demonstrated that the Fedorov-Groth law is valid and statistically meaningful, when chemical complexity is expressed as the amount of Shannon chemical information per atom and the degree of symmetry as the order of the point group of a mineral.

Identifiants

pubmed: 32356793
pii: S2053273320004209
doi: 10.1107/S2053273320004209
pmc: PMC7233019
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

429-431

Subventions

Organisme : Russian Science Foundation
ID : 19-17-00038

Références

Acta Crystallogr A. 2012 May;68(Pt 3):393-8
pubmed: 22514071
Angew Chem Int Ed Engl. 2014 Jan 13;53(3):654-61
pubmed: 24339343
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):274-6
pubmed: 27048729

Auteurs

Sergey V Krivovichev (SV)

Department of Crystallography, Institute of Earth Sciences, St Petersburg State University, University Emb. 7/9, St Petersburg, 199034, Russian Federation.

Vladimir G Krivovichev (VG)

Department of Mineralogy, Institute of Earth Sciences, St Petersburg State University, University Emb. 7/9, St Petersburg, 199034, Russian Federation.

Classifications MeSH