Surface Adsorption and Bulk Properties of Surfactants in Quaternary-Ammonium-Salt-Type Amphiphilic Monomeric and Gemini Ionic Liquids.

The physicochemical properties of ionic liquids can be readily controlled. Currently, it is necessary to investigate the properties of different surfactants to elucidate the mixtures used in quaternary-ammonium-salt-type ionic liquids. Herein, the surface adsorption and bulk properties of homogeneous polyoxyethylene (EO)-type nonionic surfactant, quaternary-ammonium-salt-type cationic surfactant, and sulfobetaine-type zwitterionic surfactant are elucidated in quaternary-ammonium-salt-type amphiphilic monomeric ionic liquids and gemini ionic liquids with bis(fluorosulfonyl)imide or bis(trifluoromethanesulfonyl)imide as counterions. The monomeric amphiphilic ionic liquids that adsorbed at the interface were replaced with C