A convenient reagent for the conversion of aldoximes into nitriles and isonitriles.

Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
11 Jun 2020
Historique:
pubmed: 6 5 2020
medline: 6 5 2020
entrez: 6 5 2020
Statut: ppublish

Résumé

For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.

Identifiants

DOI: 10.1039/d0cc00188k PMID: 32369052
pubmed: 32369052
doi: 10.1039/d0cc00188k
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

6221-6224

Auteurs

Wei Zhang (W)

Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China. jchxiao@sioc.ac.cn.

Jin-Hong Lin (JH)

Pengfei Zhang (P)

Ji-Chang Xiao (JC)

Classifications MeSH