Boron-Mediated Carbon-Carbon Bond Cleavage and Rearrangement of Benzene Forming the Borepinyl Radical and Borole Derivatives.

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
03 Jun 2020
Historique:
pubmed: 10 5 2020
medline: 10 5 2020
entrez: 9 5 2020
Statut: ppublish

Résumé

The reaction of atomic boron with benzene in solid neon has been investigated by matrix isolation infrared spectroscopy with isotopic substitutions as well as quantum chemical calculations. The reaction is initiated by boron atom addition to benzene in forming an η

Identifiants

DOI: 10.1021/jacs.0c02131 PMID: 32383858
pubmed: 32383858
doi: 10.1021/jacs.0c02131
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

10079-10086

Auteurs

Jiwen Jian (J)

Hangzhou Institute of Advanced Studies, Zhejiang Normal University, 1108 Gengwen Road, Hangzhou 311231, China.
ORCID: 0000-0002-9268-1987

Xuan Wu (X)

Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative materials, Fudan University, Shanghai 200433, China.

Mohua Chen (M)

Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative materials, Fudan University, Shanghai 200433, China.

Mingfei Zhou (M)

Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative materials, Fudan University, Shanghai 200433, China.
ORCID: 0000-0002-1915-6203

Classifications MeSH