Cu

TEMPO asymmetric catalysis copper electrocatalysis oxidative cross-coupling

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
24 Aug 2020
Historique:
received: 08 04 2020
pubmed: 13 5 2020
medline: 13 5 2020
entrez: 13 5 2020
Statut: ppublish

Résumé

A novel strategy for asymmetric Shono-type oxidative cross-coupling has been developed by merging copper catalysis and electrochemistry, affording C1-alkynylated tetrahydroisoquinolines with good to excellent enantioselectivity. The use of TEMPO as a co-catalytic redox mediator is crucial not only for oxidizing a tetrahydroisoquinoline to an iminium ion species but also for decreasing the oxidation potential of the reaction. A novel bisoxazoline ligand is also reported.

Identifiants

pubmed: 32394631
doi: 10.1002/anie.202005099
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

15254-15259

Subventions

Organisme : National Natural Science Foundation of China
ID : 21821002, 21772222, and 91956112
Organisme : Chinese Academy of Sciences
ID : XDB20000000
Organisme : Science and Technology Commission of Shanghai Municipality
ID : 17JC1401200, 18JC1415600, and 19YF1458500

Informations de copyright

© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Auteurs

Pei-Sen Gao (PS)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Xin-Jun Weng (XJ)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Zhen-Hua Wang (ZH)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Chao Zheng (C)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Bing Sun (B)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Zhi-Hao Chen (ZH)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Shu-Li You (SL)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Tian-Sheng Mei (TS)

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Science, 345 Lingling Road, Shanghai, 200032, China.

Classifications MeSH